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| rdf:type
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| Description
| - Byla prováděna pokročilá statistická vyhodnocení konstant stability komplexů z elektroforetických dat II - diastereometrické iontové páry (R,S)-N-(3,5-dinitrobenzoyl)leucinu a terc-butylcarbamoylquininu. (cs)
- Intermolecular association and ion-pair formation, respectively, between a cationic chiral selector, viz. o-9-(tert-butylcarbamoyl) quinine (CQN), and the both enantiomers of anionic N-(3,5-dinitrobenzoyl)leucine, (R)-DNB-Leu and (S)-DNB-Leu, were investigated by affinity capillary electrophoresis (ACE). Thus, binding constants of the both diastereomeric ion-pairs, (R) and (S)-DNB-Leu/CQN associates, were determined by different experimental setups and correction of nonlinear effects. A reciprocal setup was employed for the high-affinity (S)-enantiomer, and the experimental mobility data obtained for CQN at variable (S)-DNB-Leu concentrations in the background electrolyte were linearized and evaluated by advanced statistical model. A binding constant of K-S = 125.11 mol(-1) was afforded. The constant for the (R)-enantiomer, which is outside the range suitable for direct affinity CE, was obtained from indirect affinity CE utilizing the separation of the DNB-Leu racemate at a single appropriate CQN conc
- Intermolecular association and ion-pair formation, respectively, between a cationic chiral selector, viz. o-9-(tert-butylcarbamoyl) quinine (CQN), and the both enantiomers of anionic N-(3,5-dinitrobenzoyl)leucine, (R)-DNB-Leu and (S)-DNB-Leu, were investigated by affinity capillary electrophoresis (ACE). Thus, binding constants of the both diastereomeric ion-pairs, (R) and (S)-DNB-Leu/CQN associates, were determined by different experimental setups and correction of nonlinear effects. A reciprocal setup was employed for the high-affinity (S)-enantiomer, and the experimental mobility data obtained for CQN at variable (S)-DNB-Leu concentrations in the background electrolyte were linearized and evaluated by advanced statistical model. A binding constant of K-S = 125.11 mol(-1) was afforded. The constant for the (R)-enantiomer, which is outside the range suitable for direct affinity CE, was obtained from indirect affinity CE utilizing the separation of the DNB-Leu racemate at a single appropriate CQN conc (en)
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| Title
| - Advanced statistical evaluation of the complex formation constants from electrophoretic data II - Diastereomeric ion-pairs of (R,S)-N-(3,5-dinitrobenzoyl)leucine and tert-butylcarbamoylquinine
- Advanced statistical evaluation of the complex formation constants from electrophoretic data II - Diastereomeric ion-pairs of (R,S)-N-(3,5-dinitrobenzoyl)leucine and tert-butylcarbamoylquinine (en)
- Pokročilé statistické vyhodnocení konstant stability komplexů z elektroforetických dat II - diastereometrické iontové páry (R,S)-N-(3,5-dinitrobenzoyl)leucinu a terc-butylcarbamoylquininu (cs)
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| skos:prefLabel
| - Advanced statistical evaluation of the complex formation constants from electrophoretic data II - Diastereomeric ion-pairs of (R,S)-N-(3,5-dinitrobenzoyl)leucine and tert-butylcarbamoylquinine
- Advanced statistical evaluation of the complex formation constants from electrophoretic data II - Diastereomeric ion-pairs of (R,S)-N-(3,5-dinitrobenzoyl)leucine and tert-butylcarbamoylquinine (en)
- Pokročilé statistické vyhodnocení konstant stability komplexů z elektroforetických dat II - diastereometrické iontové páry (R,S)-N-(3,5-dinitrobenzoyl)leucinu a terc-butylcarbamoylquininu (cs)
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| skos:notation
| - RIV/61989592:15310/04:00002045!RIV/2005/MSM/153105/N
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| http://linked.open.../vavai/riv/strany
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| http://linked.open...avai/riv/aktivita
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| http://linked.open...avai/riv/aktivity
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| http://linked.open...iv/cisloPeriodika
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| http://linked.open...vai/riv/dodaniDat
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| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
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| http://linked.open...iv/duvernostUdaju
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| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
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| http://linked.open...ai/riv/idVysledku
| - RIV/61989592:15310/04:00002045
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| http://linked.open...riv/jazykVysledku
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| http://linked.open.../riv/klicovaSlova
| - statistical theory of experiment;advanced statistical evaluation;binding constants;ion-pair formation constants;affinity capillary electrophoresis;leucine;tert-butyl carbamoyl quinine (en)
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| http://linked.open.../riv/klicoveSlovo
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| http://linked.open...odStatuVydavatele
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| http://linked.open...ontrolniKodProRIV
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| http://linked.open...i/riv/nazevZdroje
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| http://linked.open...in/vavai/riv/obor
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| http://linked.open...ichTvurcuVysledku
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| http://linked.open...cetTvurcuVysledku
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| http://linked.open...UplatneniVysledku
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| http://linked.open...v/svazekPeriodika
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| http://linked.open...iv/tvurceVysledku
| - Barták, Petr
- Bednář, Petr
- Kubáček, Lubomír
- Stránský, Zdeněk
- Lindner, W.
- Lammerhofer, M.
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| http://linked.open...n/vavai/riv/zamer
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| issn
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| number of pages
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| http://localhost/t...ganizacniJednotka
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