About: NICKEL(II)DITHIOCARBAMATESWITH POLYDENTATE P-LIGANDSIN THE COORDINATION SPHERE     Goto   Sponge   NotDistinct   Permalink

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Description
  • The diamagnetic nickel(II) dithiocarbamates with tridentate P,P,P-ligands of composition [Ni(bziprdtc)(triphosI)]X (bziprdtc = benzylisopropyldithiocarbamate, triphosI= C34H33P3 = bis(2-diphenylphosphinoethyl)phenylphosphine,X = Cl-, PF6-,BPh4-, ClO4-; Ph = phenyl), [Ni(tzdtc)(triphosI)]X (tzdtc = thiazolidinedithiocarbamate, X = Cl-, PF6-), [Ni(hmidtc)(triphosI)]X (hmidtc = hexamethyleneiminedithiocarbamate, Cl-, PF6-) and [Ni(hmidtc)(triphosII)]X (triphosII = C41H39P3 = 1,1,1-tris(diphenylphosphinomethyl)ethan, X = Cl-, PF6-) have been isolated. The compounds were studied by thermal analysis, IR and UV-VIS spectroscopy, magnetochemical and conductivity measurements. All compounds are diamagnetic, 1 : 1 electrolytes, with coordination number five ofnickel in the NiS2P3 chromophore.
  • The diamagnetic nickel(II) dithiocarbamates with tridentate P,P,P-ligands of composition [Ni(bziprdtc)(triphosI)]X (bziprdtc = benzylisopropyldithiocarbamate, triphosI= C34H33P3 = bis(2-diphenylphosphinoethyl)phenylphosphine,X = Cl-, PF6-,BPh4-, ClO4-; Ph = phenyl), [Ni(tzdtc)(triphosI)]X (tzdtc = thiazolidinedithiocarbamate, X = Cl-, PF6-), [Ni(hmidtc)(triphosI)]X (hmidtc = hexamethyleneiminedithiocarbamate, Cl-, PF6-) and [Ni(hmidtc)(triphosII)]X (triphosII = C41H39P3 = 1,1,1-tris(diphenylphosphinomethyl)ethan, X = Cl-, PF6-) have been isolated. The compounds were studied by thermal analysis, IR and UV-VIS spectroscopy, magnetochemical and conductivity measurements. All compounds are diamagnetic, 1 : 1 electrolytes, with coordination number five ofnickel in the NiS2P3 chromophore. (en)
Title
  • NICKEL(II)DITHIOCARBAMATESWITH POLYDENTATE P-LIGANDSIN THE COORDINATION SPHERE
  • NICKEL(II)DITHIOCARBAMATESWITH POLYDENTATE P-LIGANDSIN THE COORDINATION SPHERE (en)
skos:prefLabel
  • NICKEL(II)DITHIOCARBAMATESWITH POLYDENTATE P-LIGANDSIN THE COORDINATION SPHERE
  • NICKEL(II)DITHIOCARBAMATESWITH POLYDENTATE P-LIGANDSIN THE COORDINATION SPHERE (en)
skos:notation
  • RIV/61989592:15310/02:00001601!RIV/2003/MSM/153103/N
http://linked.open.../vavai/riv/strany
  • 37-41
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM 153100007)
http://linked.open...iv/cisloPeriodika
  • N
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 655658
http://linked.open...ai/riv/idVysledku
  • RIV/61989592:15310/02:00001601
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • nickel II complexes; dithiocarbamates; NiS2P2 chromophore (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [83398FBDD11D]
http://linked.open...i/riv/nazevZdroje
  • Acta Universitatis Palackianae Olomucensis, Facultas Rerum Naturalium, Chemica
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 41
http://linked.open...iv/tvurceVysledku
  • Pastorek, Richard
  • Kameníček, Jiří
  • Šindelář, Zdeněk
  • Pavlíček, Marek
  • Husárek, Josef
http://linked.open...n/vavai/riv/zamer
issn
  • 0232-0061
number of pages
http://localhost/t...ganizacniJednotka
  • 15310
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