About: Syntheses and structure of Ni(III) complexes with 1-toluene 3,4-dithiole. Bond-valence approach to the oxidation state of the central atom     Goto   Sponge   NotDistinct   Permalink

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  • The complex compounds of the formula (R)[Ni-III(tdt)(2)], R = Met(4)N (I), Et4N (II), Pr4N (III), MePh3P (IV), Ph4P (V); tdt = 1-toluene-3,4-dithiole have been synthesized. The crystal structures of the compounds III and IV were determined by X-rays studies. Bond valence as a function of inter-nuclear distance for Ni-S bonds was estimated. On the basis of physico-chemical measurements and bond-valence sum model, the formal oxidation state III of Ni atoms for both structures was proposed.
  • The complex compounds of the formula (R)[Ni-III(tdt)(2)], R = Met(4)N (I), Et4N (II), Pr4N (III), MePh3P (IV), Ph4P (V); tdt = 1-toluene-3,4-dithiole have been synthesized. The crystal structures of the compounds III and IV were determined by X-rays studies. Bond valence as a function of inter-nuclear distance for Ni-S bonds was estimated. On the basis of physico-chemical measurements and bond-valence sum model, the formal oxidation state III of Ni atoms for both structures was proposed. (en)
Title
  • Syntheses and structure of Ni(III) complexes with 1-toluene 3,4-dithiole. Bond-valence approach to the oxidation state of the central atom
  • Syntheses and structure of Ni(III) complexes with 1-toluene 3,4-dithiole. Bond-valence approach to the oxidation state of the central atom (en)
skos:prefLabel
  • Syntheses and structure of Ni(III) complexes with 1-toluene 3,4-dithiole. Bond-valence approach to the oxidation state of the central atom
  • Syntheses and structure of Ni(III) complexes with 1-toluene 3,4-dithiole. Bond-valence approach to the oxidation state of the central atom (en)
skos:notation
  • RIV/61989592:15310/02:00001531!RIV/2003/MSM/153103/N
http://linked.open.../vavai/riv/strany
  • 483-490
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM 153100007)
http://linked.open...iv/cisloPeriodika
  • 4
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 666092
http://linked.open...ai/riv/idVysledku
  • RIV/61989592:15310/02:00001531
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • nickel(III)dithiolene complexes; crystal structure; synthesis; physico-chemical measurements; bond valences (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • PL - Polská republika
http://linked.open...ontrolniKodProRIV
  • [62C590BDBAF2]
http://linked.open...i/riv/nazevZdroje
  • Polish Journal of Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 76
http://linked.open...iv/tvurceVysledku
  • Kameníček, Jiří
  • Žák, Zdirad
  • Kratochvil, Bohumil
  • Valach, Fedor
http://linked.open...n/vavai/riv/zamer
issn
  • 0137-5083
number of pages
http://localhost/t...ganizacniJednotka
  • 15310
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