About: Synthesis, structure and magnetic behaviour of a two dimensional cyano-bridged complex [{Cu(ept)}(3)Fe(CN)(6)] (ClO4)(2)center dot 5H(2)O [ept = N-(2-aminoethyl)-1,3 diaminopropane]

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About: Synthesis, structure and magnetic behaviour of a two dimensional cyano-bridged complex [{Cu(ept)}(3)Fe(CN)(6)] (ClO4)(2)center dot 5H(2)O [ept = N-(2-aminoethyl)-1,3 diaminopropane] Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The bimetallic compound [{Cu(ept)}(3)Fe(CN)(6)](ClO4)(2). 5H(2)O [ept = N-(2-aminoethyl)-1,3-diaminopropane] has been prepared from the reaction of Cu(ClO4)(2). 6H(2)O, ept and K-4[Fe(CN)(6)]. 3H(2)O in water and its crystal and molecular structure has been determined. The structure consists of a two-dimensional network formed by [{Cu(ept)}(3)Fe(CN)(6)](2+) moieties, perchlorate anions and water molecules. Every [Fe(CN)(6)](4-) anion is coordinated by six [Cu(ept)](2+) cations through six cyano nitrogens, providing a 2D sheet structure extended by Fe-(CN)-Cu linkages. All the copper(II) ions are five-coordinated by three ept nitrogen and two cyanide nitrogen atoms in a distorted square-pyramidal arrangement. The EPR spectrum of the compound at room temperature also confirms the coordination environment of the copper(II) atoms. A magnetic susceptibility measurement of the complex was performed down to 4 K but no coupling was found among the copper atoms via the -(NC)-Fe-(CN)- bridges. The bimetallic compound [{Cu(ept)}(3)Fe(CN)(6)](ClO4)(2). 5H(2)O [ept = N-(2-aminoethyl)-1,3-diaminopropane] has been prepared from the reaction of Cu(ClO4)(2). 6H(2)O, ept and K-4[Fe(CN)(6)]. 3H(2)O in water and its crystal and molecular structure has been determined. The structure consists of a two-dimensional network formed by [{Cu(ept)}(3)Fe(CN)(6)](2+) moieties, perchlorate anions and water molecules. Every [Fe(CN)(6)](4-) anion is coordinated by six [Cu(ept)](2+) cations through six cyano nitrogens, providing a 2D sheet structure extended by Fe-(CN)-Cu linkages. All the copper(II) ions are five-coordinated by three ept nitrogen and two cyanide nitrogen atoms in a distorted square-pyramidal arrangement. The EPR spectrum of the compound at room temperature also confirms the coordination environment of the copper(II) atoms. A magnetic susceptibility measurement of the complex was performed down to 4 K but no coupling was found among the copper atoms via the -(NC)-Fe-(CN)- bridges. (en)
Title	Synthesis, structure and magnetic behaviour of a two dimensional cyano-bridged complex [{Cu(ept)}(3)Fe(CN)(6)] (ClO4)(2)center dot 5H(2)O [ept = N-(2-aminoethyl)-1,3 diaminopropane] Synthesis, structure and magnetic behaviour of a two dimensional cyano-bridged complex [{Cu(ept)}(3)Fe(CN)(6)] (ClO4)(2)center dot 5H(2)O [ept = N-(2-aminoethyl)-1,3 diaminopropane] (en)
skos:prefLabel	Synthesis, structure and magnetic behaviour of a two dimensional cyano-bridged complex [{Cu(ept)}(3)Fe(CN)(6)] (ClO4)(2)center dot 5H(2)O [ept = N-(2-aminoethyl)-1,3 diaminopropane] Synthesis, structure and magnetic behaviour of a two dimensional cyano-bridged complex [{Cu(ept)}(3)Fe(CN)(6)] (ClO4)(2)center dot 5H(2)O [ept = N-(2-aminoethyl)-1,3 diaminopropane] (en)
skos:notation	RIV/61989592:15310/01:00001667!RIV/2003/MSM/153103/N
http://linked.open.../vavai/riv/strany	655-658
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM 153100007)
http://linked.open...iv/cisloPeriodika	4
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Smékal, Zdeněk Trávníček, Zdeněk
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	698146
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/01:00001667
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Crystals-structure; Prussian Blue (en)
http://linked.open.../riv/klicoveSlovo	Prussian Blue Crystals-structure
http://linked.open...odStatuVydavatele	FR - Francouzská republika
http://linked.open...ontrolniKodProRIV	[63E85F56F232]
http://linked.open...i/riv/nazevZdroje	New Journal of Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...UplatneniVysledku	2001
http://linked.open...v/svazekPeriodika	25
http://linked.open...iv/tvurceVysledku	Marek, Jaromír Smékal, Zdeněk Trávníček, Zdeněk Escuer, Albert
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20153100007
issn	1144-0546
number of pages	4 (xsd:int)
http://localhost/t...ganizacniJednotka	15310

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