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  • There is a large amount of research and application studies in the topic of organically modified vermiculites and their properties. In this work, the stability of two organovermiculites, one modified with hexadecyltrimethylammonium (HDTMA + )andtheothermodified with hexadecylpyridinium (HDP +) ions,wasinvestigatedatpHvaluesfrom1 to 14 at laboratory temperature. The organovermiculites in the pH range of 4–10 were stable. In addition, the HDTMA + - vermiculite was stable in strong alkaline media and under extreme acidic conditions as well. However, HDP +-vermiculite underwent significant decomposition when exposed to strong acidic or alkaline conditions (pH 1, 2 and 12, 14). The prepared and tested materials were investigated using X-ray diffraction (XRD) method, Fourier transform infrared (FTIR) spectrometry, total organic carbon content (TOC), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The leaching of structural cations was determined as well.
  • There is a large amount of research and application studies in the topic of organically modified vermiculites and their properties. In this work, the stability of two organovermiculites, one modified with hexadecyltrimethylammonium (HDTMA + )andtheothermodified with hexadecylpyridinium (HDP +) ions,wasinvestigatedatpHvaluesfrom1 to 14 at laboratory temperature. The organovermiculites in the pH range of 4–10 were stable. In addition, the HDTMA + - vermiculite was stable in strong alkaline media and under extreme acidic conditions as well. However, HDP +-vermiculite underwent significant decomposition when exposed to strong acidic or alkaline conditions (pH 1, 2 and 12, 14). The prepared and tested materials were investigated using X-ray diffraction (XRD) method, Fourier transform infrared (FTIR) spectrometry, total organic carbon content (TOC), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The leaching of structural cations was determined as well. (en)
Title
  • The influence of pH on organogravermiculite structure stability
  • The influence of pH on organogravermiculite structure stability (en)
skos:prefLabel
  • The influence of pH on organogravermiculite structure stability
  • The influence of pH on organogravermiculite structure stability (en)
skos:notation
  • RIV/61989100:27710/14:86092713!RIV15-MSM-27710___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(ED2.1.00/03.0069)
http://linked.open...iv/cisloPeriodika
  • 93-94
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 21546
http://linked.open...ai/riv/idVysledku
  • RIV/61989100:27710/14:86092713
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • pH, Vermiculite, Organovermiculite, HDTMA, HDP, Stability (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [4027FFC53E8A]
http://linked.open...i/riv/nazevZdroje
  • Applied Clay Science
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 1
http://linked.open...iv/tvurceVysledku
  • Plachá, Daniela
  • Simha Martynková, Gražyna
  • Seidlerová, Jana
  • Peikertová, Pavlína
  • Alicja, Bachmatiuk
  • Mark H., Rummeli
issn
  • 0169-1317
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.clay.2014.03.008
http://localhost/t...ganizacniJednotka
  • 27710
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