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| Description
| - Cílem práce bylo prozkoumat možnost intekalace 1H-imidazolu a jeho derivátu 2-fenylimidazolu do mezivrství montmorillonitu (člen dioktaedrální smektitové skupiny) a možnost in situ tvorby Cu komplexů těchto sloučenin v mezivrství Cu(II)-montmorillonitu. Cu(II)-montmorillonit byl připraven z přírodního Ca-montmorillonitu z oblasti Ivančice v České Republice (jež byl frakcionován pod méně než < 45 m) kationtově výměnnou reakcí ve vodném roztoku CuCl2.2H2O. Interkalace 1H-imidazolu (IM) a 2-fenylimidazolu (2-PhIM) do mezivrství přírodního Ca-montmorillonitu (Ca-MMT) a kationtově vyměněného Cu(II)-montmorillonitu (Cu-MMT) byla provedena dvěma cestami, melt interkalací a interkalací z roztoku. Pouze prezentovaná interkalace IM a 2-PhIM do mezivrství Ca-MMT a Cu-MMT v pevné fázi poskytovala požadované výsledky, což bylo doloženo jako rozšíření mezivrstevní vzdálenosti pomocí rentgenové práškové difrakce. Předpokládáme, že v jílovém mezivrství vzniká laterální dvojvrstva interkalovaných mol (cs)
- The aim of this study was to investigate a possibility of intercalation of the 1H-imidazole and his derivative 2-phenylimidazole into the interlayer space of montmorillonite (a member of dioctahedral smectite group) and a possibility of in situ formation Cu complexes of these compounds in the interlayer space of Cu(II)-montmorillonite. Cu(II)-montmorillonite was prepared from natural Ca-montmorillonite (Ivančice region, Czech Republic) (fraction < 45 m) using the method of cation exchange reaction in an aqueous solution of CuCl2.2H2O. Intercalation of 1H-imidazole (IM) and 2-phenylimidazole (2-PhIM) into the interlayer spaces of both natural Ca-montmorillonite (Ca-MMT) and Cu(II)-montmorillonite (Cu-MMT) was carried out by two ways, melt intercalation and intercalation from solution. Only the presented melt intercalation of IM and 2-PhIM into the interlayer spaces of Ca-MMT and Cu-MMT gave required results, it has been confirmed observing an increase of the clay interlayer spacing us
- The aim of this study was to investigate a possibility of intercalation of the 1H-imidazole and his derivative 2-phenylimidazole into the interlayer space of montmorillonite (a member of dioctahedral smectite group) and a possibility of in situ formation Cu complexes of these compounds in the interlayer space of Cu(II)-montmorillonite. Cu(II)-montmorillonite was prepared from natural Ca-montmorillonite (Ivančice region, Czech Republic) (fraction < 45 m) using the method of cation exchange reaction in an aqueous solution of CuCl2.2H2O. Intercalation of 1H-imidazole (IM) and 2-phenylimidazole (2-PhIM) into the interlayer spaces of both natural Ca-montmorillonite (Ca-MMT) and Cu(II)-montmorillonite (Cu-MMT) was carried out by two ways, melt intercalation and intercalation from solution. Only the presented melt intercalation of IM and 2-PhIM into the interlayer spaces of Ca-MMT and Cu-MMT gave required results, it has been confirmed observing an increase of the clay interlayer spacing us (en)
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| Title
| - Clay-supported imidazole-copper complexes
- Clay-supported imidazole-copper complexes (en)
- Komplexy imidazol-měď na bázi jílů (cs)
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| skos:prefLabel
| - Clay-supported imidazole-copper complexes
- Clay-supported imidazole-copper complexes (en)
- Komplexy imidazol-měď na bázi jílů (cs)
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| skos:notation
| - RIV/61989100:27640/07:00015164!RIV08-GA0-27640___
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| http://linked.open.../vavai/riv/strany
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| http://linked.open...avai/riv/aktivita
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| http://linked.open...avai/riv/aktivity
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| http://linked.open...iv/cisloPeriodika
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| http://linked.open...vai/riv/dodaniDat
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| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
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| http://linked.open...iv/duvernostUdaju
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| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
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| http://linked.open...ai/riv/idVysledku
| - RIV/61989100:27640/07:00015164
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| http://linked.open...riv/jazykVysledku
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| http://linked.open.../riv/klicovaSlova
| - heterogeneous catalysts; imidazole; montmorillonite; intercalation. (en)
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| http://linked.open.../riv/klicoveSlovo
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| http://linked.open...odStatuVydavatele
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| http://linked.open...ontrolniKodProRIV
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| http://linked.open...i/riv/nazevZdroje
| - Acta Metallurgica Slovaca
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| http://linked.open...in/vavai/riv/obor
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| http://linked.open...ichTvurcuVysledku
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| http://linked.open...cetTvurcuVysledku
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| http://linked.open...vavai/riv/projekt
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| http://linked.open...UplatneniVysledku
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| http://linked.open...v/svazekPeriodika
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| http://linked.open...iv/tvurceVysledku
| - Simha Martynková, Gražyna
- Šenauerová, Sylva
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| issn
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| number of pages
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| http://localhost/t...ganizacniJednotka
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