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  • Five well and poor ordered kaolinites were studied to explore structural changes of kaolinite/formamide intercalates and de-intercalates. These materials were evaluated using the X-ray powder diffraction (XRPD) supplement with scanning electron microscope (SEM), measurement of specific surface area (SSA) and particle size distribution (PSD). The XRPD of de-intercalated kaolinites exhibit: (1) diffractions of 7 Å-kaolinite, some remaining 10 Å kaolinite/formamide complex and an additional 8.4 Å phase, (2) lower one-layer thickness of de-intercalated 7 Å-kaolinite than before formamide treatment, (3) changes in the (02, 11) diffraction band indicating structural disorder in the a, b plane. The chemical activation of kaolinites using formamide creates kaolinites with smaller and more homogenous particles and higher SSA than were observed in the original ones.
  • Five well and poor ordered kaolinites were studied to explore structural changes of kaolinite/formamide intercalates and de-intercalates. These materials were evaluated using the X-ray powder diffraction (XRPD) supplement with scanning electron microscope (SEM), measurement of specific surface area (SSA) and particle size distribution (PSD). The XRPD of de-intercalated kaolinites exhibit: (1) diffractions of 7 Å-kaolinite, some remaining 10 Å kaolinite/formamide complex and an additional 8.4 Å phase, (2) lower one-layer thickness of de-intercalated 7 Å-kaolinite than before formamide treatment, (3) changes in the (02, 11) diffraction band indicating structural disorder in the a, b plane. The chemical activation of kaolinites using formamide creates kaolinites with smaller and more homogenous particles and higher SSA than were observed in the original ones. (en)
  • Kaolinity s různou strukturní neuspořádanosti byly studovány po interkalaci a de-interkalaci formamidu. Připravené kaolinit/formamidové interkaláty a de-interkaláty byly hodnoceny rentgenovou práškovou difrakční (XRPD) analýzou a doplněny hodnotami z měření specifického povrchu (SSA) a údaji o distribuci velikosti částic (PSD). Tvar částic byl hodnocen pod elektronovým mikroskopem (SEM). XRPD analýza de-interkalovaných kaolinitů ukázala, že: (1) vedle 7 Å-kaolinitu jsou přítomny zbytek 10-Å kaolinit/formamidového interkalátu a nově vzniklá 8.4-Å fáze, (2) výška mezivrství u de-interkalovaného 7-Å kaolinitu je menší ve srovnání s původním kaolinitem, (3) změny v difrakčním pásu (02, 11) jsou výsledkem strukturní neuspořádanosti v horizontální rovině a, b. Aktivované kaolinity po de-interkalaci formamidu mají ve srovnání s původním kaolinitem jednodušší částice a větší specifický povrch. (cs)
Title
  • Chemically activated kaolinites after de-intercalation of formamide
  • Chemically activated kaolinites after de-intercalation of formamide (en)
  • Chemická aktivace kaolinitů po de-interkalaci formamidu z kaolint/formamidových interkalátů (cs)
skos:prefLabel
  • Chemically activated kaolinites after de-intercalation of formamide
  • Chemically activated kaolinites after de-intercalation of formamide (en)
  • Chemická aktivace kaolinitů po de-interkalaci formamidu z kaolint/formamidových interkalátů (cs)
skos:notation
  • RIV/61989100:27640/07:00015157!RIV08-GA0-27640___
http://linked.open.../vavai/riv/strany
  • 24-29
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA205/05/2548)
http://linked.open...iv/cisloPeriodika
  • 51
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 413465
http://linked.open...ai/riv/idVysledku
  • RIV/61989100:27640/07:00015157
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Powders-chemical preparation; De-intercalation; X-ray diffraction; Kaolinite; Structural application (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [34695F8C5E0E]
http://linked.open...i/riv/nazevZdroje
  • Ceramics-Silikáty
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 2007
http://linked.open...iv/tvurceVysledku
  • Kratošová, Gabriela
  • Matějka, Vlastimil
  • Simha Martynková, Gražyna
  • Valášková, Marta
issn
  • 0862-5468
number of pages
http://localhost/t...ganizacniJednotka
  • 27640
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