About: Effect of CaO on retention of S, Cl, Br, As, Mn, V, Cr, Ni, Cu, Zn, W and Pb in bottom ashes from fluidised-bed coal combustion power station     Goto   Sponge   NotDistinct   Permalink

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  • This work was conducted to evaluate whether Ca-bearing additives used during coal combustion can also help with the retention of some other elements. Since results described in the literature have usually been obtained by means of bench-scale/pilot-scale combustion facilities, this work focused on the evaluation of bottom ashes collected during four full-scale combustion tests at an operating thermal fluidized-bed power station. Bottom ashes were preferred to fly ashes for the study to avoid interference from condensation processes usually occurring in the post-combustion zone. This work focused on the behavior of S, Cl, Br, As, Mn, V, Cr, Ni, Cu, Zn, W, and Pb. Strong positive correlation with CaO content in bottom ashes was observed (for all four combustion tests) for S, As, Cl and Br (R = 0.917-0.999). Strong inverse proportionality was calculated between the contents of Pb, Zn, Ni, Cr and Mn and CaO content, so these elements showed association to materials other than Ca-bearing compounds (e.g. to aluminosilicates, organic matter etc.). Somewhat unclear behavior was observed for W, Cu, and V. Their correlation coefficients were evaluated as statistically “not significant”, i.e. these elements were not thought to be significantly associated with CaO. It was also discovered that major enrichment of CaO in the finest bottom ash fractions could be advantageously used for simple separation of elements strongly associated with these fractions, mainly S and As, but also Cl or Br. Removal of 5% of the finest ash particles brings about a decrease in As concentration down to 77%-80% of its original bulk ash content, which can be conveniently used e.g. when high As content complicates further ash utilization.
  • This work was conducted to evaluate whether Ca-bearing additives used during coal combustion can also help with the retention of some other elements. Since results described in the literature have usually been obtained by means of bench-scale/pilot-scale combustion facilities, this work focused on the evaluation of bottom ashes collected during four full-scale combustion tests at an operating thermal fluidized-bed power station. Bottom ashes were preferred to fly ashes for the study to avoid interference from condensation processes usually occurring in the post-combustion zone. This work focused on the behavior of S, Cl, Br, As, Mn, V, Cr, Ni, Cu, Zn, W, and Pb. Strong positive correlation with CaO content in bottom ashes was observed (for all four combustion tests) for S, As, Cl and Br (R = 0.917-0.999). Strong inverse proportionality was calculated between the contents of Pb, Zn, Ni, Cr and Mn and CaO content, so these elements showed association to materials other than Ca-bearing compounds (e.g. to aluminosilicates, organic matter etc.). Somewhat unclear behavior was observed for W, Cu, and V. Their correlation coefficients were evaluated as statistically “not significant”, i.e. these elements were not thought to be significantly associated with CaO. It was also discovered that major enrichment of CaO in the finest bottom ash fractions could be advantageously used for simple separation of elements strongly associated with these fractions, mainly S and As, but also Cl or Br. Removal of 5% of the finest ash particles brings about a decrease in As concentration down to 77%-80% of its original bulk ash content, which can be conveniently used e.g. when high As content complicates further ash utilization. (en)
Title
  • Effect of CaO on retention of S, Cl, Br, As, Mn, V, Cr, Ni, Cu, Zn, W and Pb in bottom ashes from fluidised-bed coal combustion power station
  • Effect of CaO on retention of S, Cl, Br, As, Mn, V, Cr, Ni, Cu, Zn, W and Pb in bottom ashes from fluidised-bed coal combustion power station (en)
skos:prefLabel
  • Effect of CaO on retention of S, Cl, Br, As, Mn, V, Cr, Ni, Cu, Zn, W and Pb in bottom ashes from fluidised-bed coal combustion power station
  • Effect of CaO on retention of S, Cl, Br, As, Mn, V, Cr, Ni, Cu, Zn, W and Pb in bottom ashes from fluidised-bed coal combustion power station (en)
skos:notation
  • RIV/61989100:27360/14:86091557!RIV15-MSM-27360___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(LO1203)
http://linked.open...iv/cisloPeriodika
  • 7
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 13156
http://linked.open...ai/riv/idVysledku
  • RIV/61989100:27360/14:86091557
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • trace elements; fluidized-bed; retention; CaO; bromine; chlorine; arsenic; coal combustion (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CN - Čínská lidová republika
http://linked.open...ontrolniKodProRIV
  • [F7AFFC78793C]
http://linked.open...i/riv/nazevZdroje
  • Journal of Environmental Sciences
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 26
http://linked.open...iv/tvurceVysledku
  • Klika, Zdeněk
  • Bartoňová, Lucie
http://linked.open...ain/vavai/riv/wos
  • 000339036500008
issn
  • 1001-0742
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.jes.2014.05.008
http://localhost/t...ganizacniJednotka
  • 27360
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