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  • Problems of reactive diffusion at the solid phase and melt contact are studied theoretically. The rate constant is a fundamental parameter characterizing the dissolving rate at a certain configuration of experiment. Relationships between the solid phase dissolving rate, i.e. the solid phase interface boundary movement in the melt, and rates of growth of intermetallic phases in the metal (Cu) are observed. This procedure enables the creation of surface and subsurface layers of regulated thickness in metallic materials by means of reactive diffusion. The main intention was an experimental study of copper dissolving in melts of various solder alloys and the related reactive diffusion. We used Sn, Sn–Cu, Sn–Ag–Cu, Sn–Zn and Sn–In alloys as a solder material. The problems that need to be solved preferentially are emphasized. It concerns especially the determination of the rate constant of dissolving and verifying whether the proposed model equations can be used for this constant determination in cases of cylindrical and planar dissolving. Rapid growth of phases in the metal (Cu) and determination of the thickness of layers with these phases pose considerable time demands to X-ray microanalyses (WDX, EDX, BSE, SEM) of specimens after their long-time heating.
  • Problems of reactive diffusion at the solid phase and melt contact are studied theoretically. The rate constant is a fundamental parameter characterizing the dissolving rate at a certain configuration of experiment. Relationships between the solid phase dissolving rate, i.e. the solid phase interface boundary movement in the melt, and rates of growth of intermetallic phases in the metal (Cu) are observed. This procedure enables the creation of surface and subsurface layers of regulated thickness in metallic materials by means of reactive diffusion. The main intention was an experimental study of copper dissolving in melts of various solder alloys and the related reactive diffusion. We used Sn, Sn–Cu, Sn–Ag–Cu, Sn–Zn and Sn–In alloys as a solder material. The problems that need to be solved preferentially are emphasized. It concerns especially the determination of the rate constant of dissolving and verifying whether the proposed model equations can be used for this constant determination in cases of cylindrical and planar dissolving. Rapid growth of phases in the metal (Cu) and determination of the thickness of layers with these phases pose considerable time demands to X-ray microanalyses (WDX, EDX, BSE, SEM) of specimens after their long-time heating. (en)
Title
  • Reactive Diffusion at the Contact of a Solid Phase with the Solder Melt
  • Reactive Diffusion at the Contact of a Solid Phase with the Solder Melt (en)
skos:prefLabel
  • Reactive Diffusion at the Contact of a Solid Phase with the Solder Melt
  • Reactive Diffusion at the Contact of a Solid Phase with the Solder Melt (en)
skos:notation
  • RIV/61989100:27360/12:86084322!RIV13-MSM-27360___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(OC08032), Z(MSM6198910013)
http://linked.open...iv/cisloPeriodika
  • Neuveden
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 164193
http://linked.open...ai/riv/idVysledku
  • RIV/61989100:27360/12:86084322
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • interdiffusion coefficient.; rate constant of dissolving; melt; lead-free solders; silver; indium; tin; copper; planar dissolving; cylindrical dissolving; Reactive diffusion (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV
  • [94AE82BD2D39]
http://linked.open...i/riv/nazevZdroje
  • Defect and Diffusion Forum
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 322
http://linked.open...iv/tvurceVysledku
  • Drápala, Jaromír
  • Konečná, Kateřina
  • Kostiuková, Gabriela
  • Petlák, Daniel
  • Vodárek, Vlastimil
  • Harcuba, P.
  • Kubíček, P.
  • Jopek, P.
http://linked.open...n/vavai/riv/zamer
issn
  • 1012-0386
number of pages
http://bibframe.org/vocab/doi
  • 10.4028/www.scientific.net/DDF.322.41
http://localhost/t...ganizacniJednotka
  • 27360
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