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  • Hg(II) ions dissolved in aqueous solutions were adsorbed by montmorillonite (MMT). The Hg(II) ion-exchange was strongly limited by the competition with H+ ions: the maximal amounts of adsorbed Hg(II) and H+ ions were 0.21 mmol g-1 and 1.10 mmol g-1, respectively. MMTs saturated with Hg(II) (Hg-MMTs) were examined by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy and thermal analysis. Hg(II) ions, such as Hg2+ and [Hg(OH)+], along with H+ ones were mostly adsorbed on permanent sites (75 % of cation exchange capacity (CEC)) and also on pH dependent surface sites (25 % of CEC). While heating, Hg-MMTs was loosing their mass up to 700 °C as a result of the MMT dehydration and dehydroxylation accompanied by release of adsorbed Hg(II).
  • Hg(II) ions dissolved in aqueous solutions were adsorbed by montmorillonite (MMT). The Hg(II) ion-exchange was strongly limited by the competition with H+ ions: the maximal amounts of adsorbed Hg(II) and H+ ions were 0.21 mmol g-1 and 1.10 mmol g-1, respectively. MMTs saturated with Hg(II) (Hg-MMTs) were examined by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy and thermal analysis. Hg(II) ions, such as Hg2+ and [Hg(OH)+], along with H+ ones were mostly adsorbed on permanent sites (75 % of cation exchange capacity (CEC)) and also on pH dependent surface sites (25 % of CEC). While heating, Hg-MMTs was loosing their mass up to 700 °C as a result of the MMT dehydration and dehydroxylation accompanied by release of adsorbed Hg(II). (en)
Title
  • Montmorillonite ion exchanged by mercury (II)
  • Montmorillonite ion exchanged by mercury (II) (en)
skos:prefLabel
  • Montmorillonite ion exchanged by mercury (II)
  • Montmorillonite ion exchanged by mercury (II) (en)
skos:notation
  • RIV/61989100:27360/12:86083740!RIV13-MSM-27360___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(ED0040/01/01)
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 151777
http://linked.open...ai/riv/idVysledku
  • RIV/61989100:27360/12:86083740
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Hg(II), montmorillonite, ion exchange, hydrogen ions, surface complexes. (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [49613D128C8E]
http://linked.open...i/riv/nazevZdroje
  • Acta Geodynamica et Geomaterialia
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 9
http://linked.open...iv/tvurceVysledku
  • Praus, Petr
  • Ritz, Michal
  • Motáková, Marcela
http://linked.open...ain/vavai/riv/wos
  • 000303781700006
issn
  • 1214-9705
number of pages
http://localhost/t...ganizacniJednotka
  • 27360
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