About: Effect of hydrothermal treatment on properties of Ni-Al layered double hydroxides and related mixed oxides     Goto   Sponge   NotDistinct   Permalink

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  • The Ni-Al layered double hydroxides (LDHs) with Ni/Al molar ratio of 2, 3, and 4 were prepared by coprecipitation and treated under hydrothermal conditions at 180 °C. Hydrothermal treatment increased significantly the crystallite size of coprecipitated samples. Gradual crystallization of NiO-like mixed oxide was observed at higher temperatures. Hydrothermal treatment improved thermal stability of the Ni2Al and Ni3Al LDHs but only a slight effect of hydrothermal treatment was observed with the Ni4Al sample. Hydrothermal aging of the LDHs resulted in decreasing content of the amorphous component and enhanced substitution of Al cations into NiO-like structure. The hydrothermally treated samples also exhibited a worse reducibility of Ni2+ components and an increase in pore size with increasing time of hydrothermal aging. The hydrothermal treatment of LDH precursor significantly improved the catalytic activity of Ni2Al mixed oxides in N2O decomposition.
  • The Ni-Al layered double hydroxides (LDHs) with Ni/Al molar ratio of 2, 3, and 4 were prepared by coprecipitation and treated under hydrothermal conditions at 180 °C. Hydrothermal treatment increased significantly the crystallite size of coprecipitated samples. Gradual crystallization of NiO-like mixed oxide was observed at higher temperatures. Hydrothermal treatment improved thermal stability of the Ni2Al and Ni3Al LDHs but only a slight effect of hydrothermal treatment was observed with the Ni4Al sample. Hydrothermal aging of the LDHs resulted in decreasing content of the amorphous component and enhanced substitution of Al cations into NiO-like structure. The hydrothermally treated samples also exhibited a worse reducibility of Ni2+ components and an increase in pore size with increasing time of hydrothermal aging. The hydrothermal treatment of LDH precursor significantly improved the catalytic activity of Ni2Al mixed oxides in N2O decomposition. (en)
Title
  • Effect of hydrothermal treatment on properties of Ni-Al layered double hydroxides and related mixed oxides
  • Effect of hydrothermal treatment on properties of Ni-Al layered double hydroxides and related mixed oxides (en)
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  • Effect of hydrothermal treatment on properties of Ni-Al layered double hydroxides and related mixed oxides
  • Effect of hydrothermal treatment on properties of Ni-Al layered double hydroxides and related mixed oxides (en)
skos:notation
  • RIV/61989100:27360/09:00022078!RIV10-MSM-27360___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA104/07/1400), Z(AV0Z40320502), Z(AV0Z40400503), Z(AV0Z40720504), Z(MSM6046137302), Z(MSM6198910016)
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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http://linked.open...dnocenehoVysledku
  • 312128
http://linked.open...ai/riv/idVysledku
  • RIV/61989100:27360/09:00022078
http://linked.open...riv/jazykVysledku
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  • layered double hydroxides; hydrotalcite-like compounds; thermal decomposition (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [8E380A1F5198]
http://linked.open...i/riv/nazevZdroje
  • Journal of Solid State Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 182
http://linked.open...iv/tvurceVysledku
  • Obalová, Lucie
  • Bastl, Z.
  • Kovanda, F.
  • Jirátová, Květa
  • Bezdička, P.
  • Pacultová, Kateřina
  • Grygar, T.
  • Rojka, T.
http://linked.open...ain/vavai/riv/wos
  • 000262546200004
http://linked.open...n/vavai/riv/zamer
issn
  • 0022-4596
number of pages
http://localhost/t...ganizacniJednotka
  • 27360
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