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  • The effect of pelleting pressure (0-10 MPa) during the preparation of Co-Mn-Al mixed oxide catalyst on its texture and activity for N2O catalytic decomposition was examined for small grain sizes used in laboratory experiments, and for model industry catalyst particles. Adsorption/desorption measurements of nitrogen, mercury porosimetry and helium pycnometry were used for detail characterization of porous structure. A volume of micropores of about 20 mm3 g1 was evaluated using modified BET equation. This value did practically not change with the increasing pelletization pressure except that of the sample formed at the pressure of 10 MPa. Although an increase of pelleting pressure caused an increase in bulk density and a decrease in pore size and pore volume of the prepared catalyst (resulting in lower values of N2O effective diffusion coefficient), no direct correlation between pelleting pressure used and catalyst activity has been found.
  • The effect of pelleting pressure (0-10 MPa) during the preparation of Co-Mn-Al mixed oxide catalyst on its texture and activity for N2O catalytic decomposition was examined for small grain sizes used in laboratory experiments, and for model industry catalyst particles. Adsorption/desorption measurements of nitrogen, mercury porosimetry and helium pycnometry were used for detail characterization of porous structure. A volume of micropores of about 20 mm3 g1 was evaluated using modified BET equation. This value did practically not change with the increasing pelletization pressure except that of the sample formed at the pressure of 10 MPa. Although an increase of pelleting pressure caused an increase in bulk density and a decrease in pore size and pore volume of the prepared catalyst (resulting in lower values of N2O effective diffusion coefficient), no direct correlation between pelleting pressure used and catalyst activity has been found. (en)
Title
  • N2O catalytic decomposition - effect of pelleting pressure on activity of Co-Mn-Al mixed oxide catalysts
  • N2O catalytic decomposition - effect of pelleting pressure on activity of Co-Mn-Al mixed oxide catalysts (en)
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  • N2O catalytic decomposition - effect of pelleting pressure on activity of Co-Mn-Al mixed oxide catalysts
  • N2O catalytic decomposition - effect of pelleting pressure on activity of Co-Mn-Al mixed oxide catalysts (en)
skos:notation
  • RIV/61989100:27360/09:00022015!RIV10-MSM-27360___
http://linked.open...avai/riv/aktivita
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  • P(GA104/07/1400), Z(AV0Z40720504), Z(MSM6046137302), Z(MSM6198910016)
http://linked.open...iv/cisloPeriodika
  • 2
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  • 330348
http://linked.open...ai/riv/idVysledku
  • RIV/61989100:27360/09:00022015
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  • pelleting pressure; nitrous oxide; catalytic decomposition; mixed oxide; layered double hydroxides (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • PL - Polská republika
http://linked.open...ontrolniKodProRIV
  • [1DA70662A994]
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  • Chemical Papers
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http://linked.open...v/svazekPeriodika
  • 63
http://linked.open...iv/tvurceVysledku
  • Obalová, Lucie
  • Kovanda, F.
  • Jirátová, Květa
  • Galejová, Kateřina
  • Pacultová, Kateřina
http://linked.open...ain/vavai/riv/wos
  • 000263300100011
http://linked.open...n/vavai/riv/zamer
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  • 0366-6352
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  • 27360
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