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Description
| - The removal of cesium from concentrated aqueous solutions into Ca/Mg ? bentonite for a wide range of bentonite ? to ? water (m/V) ratios was studied experimentally and theoretically. Using the batch techniques, the equilibrium of Cs uptake was measured. The nonlinear character of cesium sorption substantially influenced by the m/V ratio was observed. The experimental data were evaluated using multicomponent Langmuir isotherm and ion ? exchange model based on the ion-exchange reaction between Cs+ and M2+ (Ca2+ Mg2+) initially sorbed on bentonite. Constants k?1?,Cs = 0.521 mmol .g-1, k?2?,Cs = 968 L .mol-1, and k?2?,M = 592 L .mol-1 were obtained for Cs uptake described by multicomponent Langmuir isotherm. For the ion-exchange model, the thermodynamic equilibrium constant K = 75.5 mL .g-1 with a standard deviation of s?K = 17.4 m L .mol-1 was determined. Using t test, the calculated data of multicomponent Langmuir and ion-exchange isotherm were fit to experimental data, and the best agreement was obtain
- The removal of cesium from concentrated aqueous solutions into Ca/Mg ? bentonite for a wide range of bentonite ? to ? water (m/V) ratios was studied experimentally and theoretically. Using the batch techniques, the equilibrium of Cs uptake was measured. The nonlinear character of cesium sorption substantially influenced by the m/V ratio was observed. The experimental data were evaluated using multicomponent Langmuir isotherm and ion ? exchange model based on the ion-exchange reaction between Cs+ and M2+ (Ca2+ Mg2+) initially sorbed on bentonite. Constants k?1?,Cs = 0.521 mmol .g-1, k?2?,Cs = 968 L .mol-1, and k?2?,M = 592 L .mol-1 were obtained for Cs uptake described by multicomponent Langmuir isotherm. For the ion-exchange model, the thermodynamic equilibrium constant K = 75.5 mL .g-1 with a standard deviation of s?K = 17.4 m L .mol-1 was determined. Using t test, the calculated data of multicomponent Langmuir and ion-exchange isotherm were fit to experimental data, and the best agreement was obtain (en)
- V této práci bylo teoreticky a experimentálně studováno odstraňování cesia z vodných roztoků Ca/Mg-bentonitem připravených v širokém rozsahu poměru bentonit-voda (m/V).Využitím vsádkové techniky byla studována rovnováha Cs adsorpce. Byl pozorován nelineární charakter sorpce cesia značně ovlivňované poměrem m/V. Použitím t testu vypočtená data vícevrstvé Langmuirovy a ionto-výměnné izotermy byla přizpůsobena experimentálním datům a nejlepší shoda byla pozorována u ionto-výměnného modelu. Výsledky vykazují, že adsorpce cesia bentonitem může značně klesat v systémech s vysokým poměrem bentonit-voda (m/V) jako následek přítomnosti resorbovaných dvojmocných kationů ve vodné fázi. (cs)
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Title
| - Cesium uptake from aqueous solutions by Bentonite: A comparison of multicomponent sorption with Ion-exchange models
- Adsorpce Cesia z vodných roztoků bentonitem. Srovnání vícevrstevné sorpce s modelem výměny iontů (cs)
- Cesium uptake from aqueous solutions by Bentonite: A comparison of multicomponent sorption with Ion-exchange models (en)
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skos:prefLabel
| - Cesium uptake from aqueous solutions by Bentonite: A comparison of multicomponent sorption with Ion-exchange models
- Adsorpce Cesia z vodných roztoků bentonitem. Srovnání vícevrstevné sorpce s modelem výměny iontů (cs)
- Cesium uptake from aqueous solutions by Bentonite: A comparison of multicomponent sorption with Ion-exchange models (en)
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skos:notation
| - RIV/61989100:27360/07:00016091!RIV09-MSM-27360___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - Z(MSM6198910016), Z(MSM6840770020)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61989100:27360/07:00016091
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Cesium Uptake; Multicomponent Sorption; langmuir Isoterm; Ion-Exchange Models. (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Klika, Zdeněk
- Kraus, L.
- Vopálka, D.
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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