About: Rehydratation of calcined Mg-Al hydrotalcite in acidified chloride-containing aqueous solution     Goto   Sponge   NotDistinct   Permalink

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  • The rehydration of periclase-like Mg-Al mixed oxide obtained by calcination of hydrotalcite-like precursor with a Mg/Al molar ratio of 2 was carried out in KCl-HCl solutions at various pH and constant concentration of Cl-. A buffer equilibrium accompanied by leaching out of Mg2+ cations from the solid was observed during rehydration, when reconstruction of the layered hydrotalcite structure takes place. With increasing HCl concentration in the rehydration solution, the Mg/Al molar ratio in the obtained solid gradually decreased from about 1.5 to 0.3. An anomaly was found, when the increasing concentration of acid resulted in increasing pH of final solution. The XRD measurements showed that the initially formed hydroxide form of hydrotalcite is transformed into randomly interstratified forms of the Mg-Al hydroxide hydrate/Mg-Al chloride hydroxide hydrate, which are accompanied by the release of OH- anions into solution. The crystalline structure of rehydrated product decreased as Mg2+ cations were rele
  • The rehydration of periclase-like Mg-Al mixed oxide obtained by calcination of hydrotalcite-like precursor with a Mg/Al molar ratio of 2 was carried out in KCl-HCl solutions at various pH and constant concentration of Cl-. A buffer equilibrium accompanied by leaching out of Mg2+ cations from the solid was observed during rehydration, when reconstruction of the layered hydrotalcite structure takes place. With increasing HCl concentration in the rehydration solution, the Mg/Al molar ratio in the obtained solid gradually decreased from about 1.5 to 0.3. An anomaly was found, when the increasing concentration of acid resulted in increasing pH of final solution. The XRD measurements showed that the initially formed hydroxide form of hydrotalcite is transformed into randomly interstratified forms of the Mg-Al hydroxide hydrate/Mg-Al chloride hydroxide hydrate, which are accompanied by the release of OH- anions into solution. The crystalline structure of rehydrated product decreased as Mg2+ cations were rele (en)
  • The rehydration of periclase-like Mg-Al mixed oxide obtained by calcination of hydrotalcite-like precursor with a Mg/Al molar ratio of 2 was carried out in KCl-HCl solutions at various pH and constant concentration of Cl-. A buffer equilibrium accompanied by leaching out of Mg2+ cations from the solid was observed during rehydration, when reconstruction of the layered hydrotalcite structure takes place. With increasing HCl concentration in the rehydration solution, the Mg/Al molar ratio in the obtained solid gradually decreased from about 1.5 to 0.3. An anomaly was found, when the increasing concentration of acid resulted in increasing pH of final solution. The XRD measurements showed that the initially formed hydroxide form of hydrotalcite is transformed into randomly interstratified forms of the Mg-Al hydroxide hydrate/Mg-Al chloride hydroxide hydrate, which are accompanied by the release of OH- anions into solution. The crystalline structure of rehydrated product decreased as Mg2+ cations were rele (cs)
Title
  • Rehydratation of calcined Mg-Al hydrotalcite in acidified chloride-containing aqueous solution
  • Rehydratation of calcined Mg-Al hydrotalcite in acidified chloride-containing aqueous solution (en)
  • Rehydratace kalcinovaného Mg-Al hydrotalcitu v acidifikovaných vodných roztocích obsahujících chloridové ionty. (cs)
skos:prefLabel
  • Rehydratation of calcined Mg-Al hydrotalcite in acidified chloride-containing aqueous solution
  • Rehydratation of calcined Mg-Al hydrotalcite in acidified chloride-containing aqueous solution (en)
  • Rehydratace kalcinovaného Mg-Al hydrotalcitu v acidifikovaných vodných roztocích obsahujících chloridové ionty. (cs)
skos:notation
  • RIV/61989100:27360/07:00015990!RIV09-MSM-27360___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM6198910016)
http://linked.open...iv/cisloPeriodika
  • 9
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 447089
http://linked.open...ai/riv/idVysledku
  • RIV/61989100:27360/07:00015990
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Hydrotalcite; layered double hydroxide; rehydratation-reconstruction process (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [9159C2F9B71A]
http://linked.open...i/riv/nazevZdroje
  • Collection of Czechoslovak Chemical Communications
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 72
http://linked.open...iv/tvurceVysledku
  • Kovanda, František
  • Valášková, Marta
  • Kostura, Bruno
  • Leško, Juraj
http://linked.open...n/vavai/riv/zamer
issn
  • 0010-0765
number of pages
http://localhost/t...ganizacniJednotka
  • 27360
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