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  • An influence of inorganic compounds (Fe2O3, CaCO3, ZnO, PbO and K2CO3) on the blast furnace coke thermal oxidation in the air and in the CO2 atmosphere was investigated by means of thermal analysis. A catalytic effect showed itself at the oxidation in the air, especially with PbO and K2CO3. These compounds bring the oxidation starting temperature and activation energy down and increase the reaction rate constant most distinctly. The PbO and K2CO3 actions differ in their mechanisms. K2CO3 accelerates particularly the amorphous coke fractions oxidation. In the CO2 atmosphere an important catalytic effect occurred only with K2CO3. The PbO catalytic influence is less distinct.
  • An influence of inorganic compounds (Fe2O3, CaCO3, ZnO, PbO and K2CO3) on the blast furnace coke thermal oxidation in the air and in the CO2 atmosphere was investigated by means of thermal analysis. A catalytic effect showed itself at the oxidation in the air, especially with PbO and K2CO3. These compounds bring the oxidation starting temperature and activation energy down and increase the reaction rate constant most distinctly. The PbO and K2CO3 actions differ in their mechanisms. K2CO3 accelerates particularly the amorphous coke fractions oxidation. In the CO2 atmosphere an important catalytic effect occurred only with K2CO3. The PbO catalytic influence is less distinct. (en)
Title
  • The influence of selected oxides and carbonates on thermal oxidation of coke
  • The influence of selected oxides and carbonates on thermal oxidation of coke (en)
skos:prefLabel
  • The influence of selected oxides and carbonates on thermal oxidation of coke
  • The influence of selected oxides and carbonates on thermal oxidation of coke (en)
skos:notation
  • RIV/61989100:27360/03:00009357!RIV/2004/GA0/273604/N
http://linked.open.../vavai/riv/strany
  • 875-881
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA105/00/1698)
http://linked.open...iv/cisloPeriodika
  • 3
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 610351
http://linked.open...ai/riv/idVysledku
  • RIV/61989100:27360/03:00009357
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • coke, kinetics, thermal oxidation, thermogravimetry (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [4BED909A1367]
http://linked.open...i/riv/nazevZdroje
  • Journal of Thermal Analysis and Calorimetry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 71
http://linked.open...iv/tvurceVysledku
  • Slovák, Václav
  • Vallová, Silvie
  • Leško, Juraj
issn
  • 1418-2874
number of pages
http://localhost/t...ganizacniJednotka
  • 27360
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