About: Square-Planar Nickel(II) O,O'-Dialkyldithiophosphato Complexes with Triphenylphosphine of the Type [NiX(S2P{OR}2)(PPh3)] (X = Cl, Br, I and NCS)

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About: Square-Planar Nickel(II) O,O'-Dialkyldithiophosphato Complexes with Triphenylphosphine of the Type [NiX(S2P{OR}2)(PPh3)] (X = Cl, Br, I and NCS) Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Square-planární nikl(II) O,O '-dialkyldithiophosphato komplexy s triphenylphosphinem typu [NiX(S2P{OR}(2))(PPh3)] (X = Cl, Br, I and NCS) (cs) A series of new [NiX(S2P{O-c-Hex}2)(PPh3)](X = Cl–, Br–, I– and NCS–)(1)–(4) and [Ni(NCS)(S2P{OR}2)(PPh3)][R =n-Pr (5), i-Pr (6)] complexes has been synthesized and characterized by elemental analyses, f. i. r., i. r., u.v.–vis., 1H-, 13C{1H}- and 31P{1H}-n.m.r. spectra, magnetochemical and conductivity measurements. A single crystal X-ray analysis of [Ni(NCS)(S2P{O-n-Pr}2)(PPh3)](5) reveals the molecular structure of the complex and confirms a square-planar geometry around the central atom of nickel with the NCS anion coordinated via the nitrogen atom. A series of new [NiX(S2P{O-c-Hex}2)(PPh3)](X = Cl–, Br–, I– and NCS–)(1)–(4) and [Ni(NCS)(S2P{OR}2)(PPh3)][R =n-Pr (5), i-Pr (6)] complexes has been synthesized and characterized by elemental analyses, f. i. r., i. r., u.v.–vis., 1H-, 13C{1H}- and 31P{1H}-n.m.r. spectra, magnetochemical and conductivity measurements. A single crystal X-ray analysis of [Ni(NCS)(S2P{O-n-Pr}2)(PPh3)](5) reveals the molecular structure of the complex and confirms a square-planar geometry around the central atom of nickel with the NCS anion coordinated via the nitrogen atom. (en)
Title	Square-Planar Nickel(II) O,O'-Dialkyldithiophosphato Complexes with Triphenylphosphine of the Type [NiX(S2P{OR}2)(PPh3)] (X = Cl, Br, I and NCS) Square-planární nikl(II) O,O '-dialkyldithiophosphato komplexy s triphenylphosphinem typu [NiX(S2P{OR}(2))(PPh3)] (X = Cl, Br, I and NCS) (cs) Square-Planar Nickel(II) O,O'-Dialkyldithiophosphato Complexes with Triphenylphosphine of the Type [NiX(S2P{OR}2)(PPh3)] (X = Cl, Br, I and NCS) (en)
skos:prefLabel	Square-Planar Nickel(II) O,O'-Dialkyldithiophosphato Complexes with Triphenylphosphine of the Type [NiX(S2P{OR}2)(PPh3)] (X = Cl, Br, I and NCS) Square-planární nikl(II) O,O '-dialkyldithiophosphato komplexy s triphenylphosphinem typu [NiX(S2P{OR}(2))(PPh3)] (X = Cl, Br, I and NCS) (cs) Square-Planar Nickel(II) O,O'-Dialkyldithiophosphato Complexes with Triphenylphosphine of the Type [NiX(S2P{OR}2)(PPh3)] (X = Cl, Br, I and NCS) (en)
skos:notation	RIV/61389030:_____/04:00000298!RIV/2005/AV0/A56005/N
http://linked.open.../vavai/riv/strany	352;357
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/02/0436), Z(AV0Z5038910)
http://linked.open...iv/cisloPeriodika	4
http://linked.open...vai/riv/dodaniDat	2005
http://linked.open...aciTvurceVysledku	Trávníček, Zdeněk Szüčová, Lucie
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav experimentální botaniky AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	587592
http://linked.open...ai/riv/idVysledku	RIV/61389030:_____/04:00000298
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	nickel(II) complexes; DIALKYL DITHIOPHOSPHATES; CRYSTAL-STRUCTURE (en)
http://linked.open.../riv/klicoveSlovo	CRYSTAL-STRUCTURE nickel(II) complexes DIALKYL DITHIOPHOSPHATES
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[D0363D64A778]
http://linked.open...i/riv/nazevZdroje	Transition Metal Chemistry
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Application of Crystallographic Databases in Scientific Practice
http://linked.open...UplatneniVysledku	2004
http://linked.open...v/svazekPeriodika	29
http://linked.open...iv/tvurceVysledku	Trávníček, Zdeněk Marek, J. Szüčová, Lucie Maloň, M. Machala, V.
http://linked.open...n/vavai/riv/zamer	Physiological and genetical bases of plant development, cell cycle, morphogenesis, stress reactions and biotechnologies. Genome organisation and function
issn	0340-4285
number of pages	6 (xsd:int)

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