About: Syntheses and properties of binuclear copper(II) mixed-ligand complexes involving thiodiglycolic acid. The crystal structures of [(phen)2Cu(m-tdga)Cu(phen)](NO3)2x5H2O and [(H2O)(pmdien)Cu(micro-tdga)Cu(pmdien)(H2O)](ClO4).

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About: Syntheses and properties of binuclear copper(II) mixed-ligand complexes involving thiodiglycolic acid. The crystal structures of [(phen)2Cu(m-tdga)Cu(phen)](NO3)2x5H2O and [(H2O)(pmdien)Cu(micro-tdga)Cu(pmdien)(H2O)](ClO4). Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Mixed-ligand binuclear Cu(II) complexes involving thiodiglycolate(2 /) anion and nitrogen-donor ligands in the coordination sphere of composition [(phen)2Cu(m-tdga)Cu(phen)](NO3)2 /5H2O (1) and [(H2O)(pmdien)Cu(m-tdga)Cu(pmdien)(H2O)](ClO4)2 (2), where phen /1,10-phenanthroline, H2tdga /thiodiglycolic acid, pmdien /N,N,N,N-pentamethyldiethylenetriamine, have been prepared. Temperature dependence of magnetic susceptibility, EPR spectroscopy and single crystal X-ray analysis has been used to characterize these compounds. Magnetic susceptibility measurements over the 1.9 /300 K temperature range revealed a weak antiferromagnetic interaction between two copper atoms with the exchange integral value 2J=-4.80 cm-1 for 1 and -0.71 cm-1 for 2. The bridging dianion of thiodiglycolic acid is coordinated in each of the two complexes in a different manner. Mixed-ligand binuclear Cu(II) complexes involving thiodiglycolate(2 /) anion and nitrogen-donor ligands in the coordination sphere of composition [(phen)2Cu(m-tdga)Cu(phen)](NO3)2 /5H2O (1) and [(H2O)(pmdien)Cu(m-tdga)Cu(pmdien)(H2O)](ClO4)2 (2), where phen /1,10-phenanthroline, H2tdga /thiodiglycolic acid, pmdien /N,N,N,N-pentamethyldiethylenetriamine, have been prepared. Temperature dependence of magnetic susceptibility, EPR spectroscopy and single crystal X-ray analysis has been used to characterize these compounds. Magnetic susceptibility measurements over the 1.9 /300 K temperature range revealed a weak antiferromagnetic interaction between two copper atoms with the exchange integral value 2J=-4.80 cm-1 for 1 and -0.71 cm-1 for 2. The bridging dianion of thiodiglycolic acid is coordinated in each of the two complexes in a different manner. (en)
Title	Syntheses and properties of binuclear copper(II) mixed-ligand complexes involving thiodiglycolic acid. The crystal structures of [(phen)2Cu(m-tdga)Cu(phen)](NO3)2x5H2O and [(H2O)(pmdien)Cu(micro-tdga)Cu(pmdien)(H2O)](ClO4). Syntheses and properties of binuclear copper(II) mixed-ligand complexes involving thiodiglycolic acid. The crystal structures of [(phen)2Cu(m-tdga)Cu(phen)](NO3)2x5H2O and [(H2O)(pmdien)Cu(micro-tdga)Cu(pmdien)(H2O)](ClO4). (en)
skos:prefLabel	Syntheses and properties of binuclear copper(II) mixed-ligand complexes involving thiodiglycolic acid. The crystal structures of [(phen)2Cu(m-tdga)Cu(phen)](NO3)2x5H2O and [(H2O)(pmdien)Cu(micro-tdga)Cu(pmdien)(H2O)](ClO4). Syntheses and properties of binuclear copper(II) mixed-ligand complexes involving thiodiglycolic acid. The crystal structures of [(phen)2Cu(m-tdga)Cu(phen)](NO3)2x5H2O and [(H2O)(pmdien)Cu(micro-tdga)Cu(pmdien)(H2O)](ClO4). (en)
skos:notation	RIV/61389030:_____/03:56033096!RIV/2004/GA0/A56004/N
http://linked.open.../vavai/riv/strany	411;418
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/99/0067), Z(AV0Z5038910)
http://linked.open...iv/cisloPeriodika	N/A
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Trávníček, Zdeněk
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav experimentální botaniky AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	629994
http://linked.open...ai/riv/idVysledku	RIV/61389030:_____/03:56033096
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Copper(II); Thiodiglycolic acid complexes; Crystal structures (en)
http://linked.open.../riv/klicoveSlovo	Copper(II) Crystal structures Thiodiglycolic acid complexes
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[E4F628B6C34C]
http://linked.open...i/riv/nazevZdroje	Polyhedron
http://linked.open...in/vavai/riv/obor	CE
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Lease of crystallographic databases
http://linked.open...UplatneniVysledku	2003
http://linked.open...v/svazekPeriodika	22
http://linked.open...iv/tvurceVysledku	Trávníček, Zdeněk Marek, J. Kopel, P. Mrozinski, J. Korabik, M.
http://linked.open...n/vavai/riv/zamer	Physiological and genetical bases of plant development, cell cycle, morphogenesis, stress reactions and biotechnologies. Genome organisation and function
issn	0277-5387
number of pages	8 (xsd:int)

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