About: Degradation of Substituted Phenols in a hybrid gas-liquid electrical discharge reactor

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Non-thermal plasma induced decomposition of ortho-, meta-, and para- isomers of hydroxy-, chloro-, and nitro- phenols in water was investigated using the hybrid series gas-liquid electrical discharge reactor that generates gas phase discharge above the water surface simultaneously with the electrical discharge directly in the liquid. Degradation of substituted phenols was evaluated for two gas phase compositions, pure argon and pure oxygen, above the aqueous solution. Removal of all phenols was found to follow first order kinetics. Hydroquinone was the most reactive among substituted phenols under oxygen atmosphere, whereas in argon the most reactive were 4-chlorophenol and 2-nitrophenol. Electrophilic attack by hydroxyl radicals and ozone were determined to be the main oxidation pathways for degradation of phenols in the hybrid series reactor under argon and oxygen atmospheres, respectively. Non-thermal plasma induced decomposition of ortho-, meta-, and para- isomers of hydroxy-, chloro-, and nitro- phenols in water was investigated using the hybrid series gas-liquid electrical discharge reactor that generates gas phase discharge above the water surface simultaneously with the electrical discharge directly in the liquid. Degradation of substituted phenols was evaluated for two gas phase compositions, pure argon and pure oxygen, above the aqueous solution. Removal of all phenols was found to follow first order kinetics. Hydroquinone was the most reactive among substituted phenols under oxygen atmosphere, whereas in argon the most reactive were 4-chlorophenol and 2-nitrophenol. Electrophilic attack by hydroxyl radicals and ozone were determined to be the main oxidation pathways for degradation of phenols in the hybrid series reactor under argon and oxygen atmospheres, respectively. (en)
Title	Degradation of Substituted Phenols in a hybrid gas-liquid electrical discharge reactor Degradation of Substituted Phenols in a hybrid gas-liquid electrical discharge reactor (en)
skos:prefLabel	Degradation of Substituted Phenols in a hybrid gas-liquid electrical discharge reactor Degradation of Substituted Phenols in a hybrid gas-liquid electrical discharge reactor (en)
skos:notation	RIV/61389021:_____/05:00025646!RIV12-AV0-61389021
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(AV0Z20430508)
http://linked.open...iv/cisloPeriodika	9
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Lukeš, Petr
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyziky plazmatu AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	517154
http://linked.open...ai/riv/idVysledku	RIV/61389021:_____/05:00025646
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Corona discharge; hybrid reactor; hydroxyl radical; ozone; substituted phenols; water treatment (en)
http://linked.open.../riv/klicoveSlovo	hybrid reactor hydroxyl radical ozone water treatment Corona discharge substituted phenols
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[3587A3071573]
http://linked.open...i/riv/nazevZdroje	Industrial and Engineering Chemistry Research
http://linked.open...in/vavai/riv/obor	BL
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...UplatneniVysledku	2005
http://linked.open...v/svazekPeriodika	44
http://linked.open...iv/tvurceVysledku	Lukeš, Petr Locke, B. R.
http://linked.open...ain/vavai/riv/wos	000228604800006
http://linked.open...n/vavai/riv/zamer	Physical and chemical processes in plasmas and theis applications
issn	0888-5885
number of pages	10 (xsd:int)
http://bibframe.org/vocab/doi	10.1021/ie0491342

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