About: Synthesis, thermal, spectral and biological properties of zinc(II) 4-hydroxybenzoate complexes     Goto   Sponge   NotDistinct   Permalink

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  • New zinc(II) 4-hydroxybenzoate complex compounds with general formula [Zn(4-OHbenz)2Ln]xH2O, where 4-OHbenz = 4-hydroxybenzoate; L = isonicotinamide, N-methylnicotinamide, N,N-diethylnicotinamide, thiourea, urea, phenazone, theophylline, methyl-3-pyridylcarbamate; n = 2, 3; x = 0–3, 5, were synthesized and characterised by elemental analysis, thermal analysis and IR spectroscopy. The thermal behaviour of the prepared compounds was studied by TG/DTG and DTA methods in argon atmosphere. The thermal decomposition of hydrated compounds started with dehydration. During the thermal decomposition, organic ligand, carbon monoxide, carbon dioxide and phenol were evolved. The final solid product of the thermal decomposition was zinc or zinc oxide. The volatile gaseous product, solid intermediate products and the final product of thermal decomposition were identified by IR spectroscopy, mass spectrometry, qualitative chemical analyses and X-ray powder diffraction method. The antimicrobial activity of zinc(II) carboxylate compounds was tested against various strains of bacteria, yeasts and filamentous fungi (S. aureus, E. coli, C. parapsilosis, R. oryzae, A. alternata, M. gypseum). The presence of zinc in complexes led to the increase in their antimicrobial activity in comparison with free 4-hydroxybenzoic acid.
  • New zinc(II) 4-hydroxybenzoate complex compounds with general formula [Zn(4-OHbenz)2Ln]xH2O, where 4-OHbenz = 4-hydroxybenzoate; L = isonicotinamide, N-methylnicotinamide, N,N-diethylnicotinamide, thiourea, urea, phenazone, theophylline, methyl-3-pyridylcarbamate; n = 2, 3; x = 0–3, 5, were synthesized and characterised by elemental analysis, thermal analysis and IR spectroscopy. The thermal behaviour of the prepared compounds was studied by TG/DTG and DTA methods in argon atmosphere. The thermal decomposition of hydrated compounds started with dehydration. During the thermal decomposition, organic ligand, carbon monoxide, carbon dioxide and phenol were evolved. The final solid product of the thermal decomposition was zinc or zinc oxide. The volatile gaseous product, solid intermediate products and the final product of thermal decomposition were identified by IR spectroscopy, mass spectrometry, qualitative chemical analyses and X-ray powder diffraction method. The antimicrobial activity of zinc(II) carboxylate compounds was tested against various strains of bacteria, yeasts and filamentous fungi (S. aureus, E. coli, C. parapsilosis, R. oryzae, A. alternata, M. gypseum). The presence of zinc in complexes led to the increase in their antimicrobial activity in comparison with free 4-hydroxybenzoic acid. (en)
Title
  • Synthesis, thermal, spectral and biological properties of zinc(II) 4-hydroxybenzoate complexes
  • Synthesis, thermal, spectral and biological properties of zinc(II) 4-hydroxybenzoate complexes (en)
skos:prefLabel
  • Synthesis, thermal, spectral and biological properties of zinc(II) 4-hydroxybenzoate complexes
  • Synthesis, thermal, spectral and biological properties of zinc(II) 4-hydroxybenzoate complexes (en)
skos:notation
  • RIV/61389013:_____/14:00427446!RIV15-AV0-61389013
http://linked.open...avai/riv/aktivita
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  • I
http://linked.open...iv/cisloPeriodika
  • 1
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  • 49065
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  • RIV/61389013:_____/14:00427446
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  • zinc; 4-hydroxybenzoate; thermal (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • HU - Maďarsko
http://linked.open...ontrolniKodProRIV
  • [AAB009D52AFF]
http://linked.open...i/riv/nazevZdroje
  • Journal of Thermal Analysis and Calorimetry
http://linked.open...in/vavai/riv/obor
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  • 116
http://linked.open...iv/tvurceVysledku
  • Kovářová, Jana
  • Györyová, K.
  • Bujdošová, Z.
  • Hudecová, D.
  • Homzová, K.
  • Vargová, Z.
  • Ganajová, M.
http://linked.open...ain/vavai/riv/wos
  • 000333533000010
issn
  • 1388-6150
number of pages
http://bibframe.org/vocab/doi
  • 10.1007/s10973-014-3702-x
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