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  • The oxidation of pyrrole with silver nitrate in the presence of suitable water-soluble polymers yields composite polypyrrole–silver colloids. The polypyrrole–silver nanoparticles stabilized with poly(N-vinylpyrrolidone) have a typical size around 350 nm and polydispersity index 0.20, i.e. a moderate polydispersity in size. Similar results have been obtained with poly(vinyl alcohol) as stabilizer. The effect of stabilizer concentration on the particle size is marginal. In the present study, several types of stabilizers have been tested in addition to currently used poly(N-vinylpyrrolidone). Transmission electron microscopy and optical microscopy revealed the gemini morphology of polypyrrole and silver colloidal nanoparticles and confirmed their size and size-distribution determined by dynamic light scattering. The use of colloidal dispersions provides an efficient tool for the UV–vis and FT Raman spectroscopic characterization of polypyrrole, including the transition between polypyrrole salt and corresponding polypyrrole base. The dispersions were used for the preparation of coatings on polyethylene terephthalate foils, and the properties for polypyrrole–silver composites have been compared with those produced from polypyrrole colloids alone.
  • The oxidation of pyrrole with silver nitrate in the presence of suitable water-soluble polymers yields composite polypyrrole–silver colloids. The polypyrrole–silver nanoparticles stabilized with poly(N-vinylpyrrolidone) have a typical size around 350 nm and polydispersity index 0.20, i.e. a moderate polydispersity in size. Similar results have been obtained with poly(vinyl alcohol) as stabilizer. The effect of stabilizer concentration on the particle size is marginal. In the present study, several types of stabilizers have been tested in addition to currently used poly(N-vinylpyrrolidone). Transmission electron microscopy and optical microscopy revealed the gemini morphology of polypyrrole and silver colloidal nanoparticles and confirmed their size and size-distribution determined by dynamic light scattering. The use of colloidal dispersions provides an efficient tool for the UV–vis and FT Raman spectroscopic characterization of polypyrrole, including the transition between polypyrrole salt and corresponding polypyrrole base. The dispersions were used for the preparation of coatings on polyethylene terephthalate foils, and the properties for polypyrrole–silver composites have been compared with those produced from polypyrrole colloids alone. (en)
Title
  • Towards conducting inks: polypyrrole-silver colloids
  • Towards conducting inks: polypyrrole-silver colloids (en)
skos:prefLabel
  • Towards conducting inks: polypyrrole-silver colloids
  • Towards conducting inks: polypyrrole-silver colloids (en)
skos:notation
  • RIV/61389013:_____/14:00426949!RIV15-GA0-61389013
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GA13-00270S), P(TE01020022), S
http://linked.open...iv/cisloPeriodika
  • 10 March
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 50814
http://linked.open...ai/riv/idVysledku
  • RIV/61389013:_____/14:00426949
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • conducting inks; polypyrrole; colloids (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [73AB8B79DD86]
http://linked.open...i/riv/nazevZdroje
  • Electrochimica acta
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 122
http://linked.open...iv/tvurceVysledku
  • Morávková, Zuzana
  • Stejskal, Jaroslav
  • Trchová, Miroslava
  • Bober, Patrycja
  • Kaplanová, M.
  • Hromádková, Jiřina
  • Omastová, M.
  • Peřinka, N.
  • Syrový, T.
http://linked.open...ain/vavai/riv/wos
  • 000334007900037
issn
  • 0013-4686
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.electacta.2013.11.037
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