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rdf:type
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Description
| - A reasonably efficient two-step synthesis of N-(2-ethylhexyl)-2,7-diiodocarbazole is presented. In the first step, the 4,4-diiodobiphenyl was nitrated to a mixture of 4,4-diiodo-2-nitrobiphenyl and 4-iodo-4-nitrobiphenyl. In the second step, the mixture of these compounds was converted by simultaneous carbazole ring closure and N-alkylation to the N-(2-ethylhexyl)-2,7-diiodocarbazole by means of tris(2-ethylhexyl) phosphite. The synthesis represents a shorter alternative to the known more tedious procedures. The prepared compound is a suitable monomer for synthesis of conjugated polymers for optoelectronic applications.
- A reasonably efficient two-step synthesis of N-(2-ethylhexyl)-2,7-diiodocarbazole is presented. In the first step, the 4,4-diiodobiphenyl was nitrated to a mixture of 4,4-diiodo-2-nitrobiphenyl and 4-iodo-4-nitrobiphenyl. In the second step, the mixture of these compounds was converted by simultaneous carbazole ring closure and N-alkylation to the N-(2-ethylhexyl)-2,7-diiodocarbazole by means of tris(2-ethylhexyl) phosphite. The synthesis represents a shorter alternative to the known more tedious procedures. The prepared compound is a suitable monomer for synthesis of conjugated polymers for optoelectronic applications. (en)
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Title
| - New two-step synthesis of N-(2-ethylhexyl)-2,7-diiodocarbazole as a monomer for conjugated polymers
- New two-step synthesis of N-(2-ethylhexyl)-2,7-diiodocarbazole as a monomer for conjugated polymers (en)
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skos:prefLabel
| - New two-step synthesis of N-(2-ethylhexyl)-2,7-diiodocarbazole as a monomer for conjugated polymers
- New two-step synthesis of N-(2-ethylhexyl)-2,7-diiodocarbazole as a monomer for conjugated polymers (en)
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skos:notation
| - RIV/61389013:_____/13:00382706!RIV13-AV0-61389013
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - I, P(1M06031), P(GAP106/12/0827), Z(AV0Z40500505)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61389013:_____/13:00382706
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - monomer synthesis; carbazole; ring closure (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Designed Monomers and Polymers
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Cimrová, Věra
- Kmínek, Ivan
- Výprachtický, Drahomír
- Kaňková, Dana
- Pokorná, Veronika
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1080/15685551.2012.705487
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