About: Rheological properties of homogeneous and heterogeneous poly(2-hydroxyethyl methacrylate) hydrogels     Goto   Sponge   NotDistinct   Permalink

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  • The swelling and rheological behaviour of hydrogels of morphology varying from non-porous to highly porous was investigated. The hydrogels were prepared by redox free radical copolymerization of 2-hydroxyethyl methacrylate with 0.1 to 5 mol% of di(ethylene glycol) dimethacrylate in the presence of water varying from 40 to 80 wt%. Various compositions led to clear, turbid or macroporous gels. The morphology of the gels was characterized using optical microscopy and cryoscan electron microscopy. The oscillatory shear and creep of swollen gels revealed that there was a pronounced difference between homogeneous or microheterogeneous and macroporous gels with communicating pores. The achievement of optimum conditions for the correct determination of shear modulus was also analysed.
  • The swelling and rheological behaviour of hydrogels of morphology varying from non-porous to highly porous was investigated. The hydrogels were prepared by redox free radical copolymerization of 2-hydroxyethyl methacrylate with 0.1 to 5 mol% of di(ethylene glycol) dimethacrylate in the presence of water varying from 40 to 80 wt%. Various compositions led to clear, turbid or macroporous gels. The morphology of the gels was characterized using optical microscopy and cryoscan electron microscopy. The oscillatory shear and creep of swollen gels revealed that there was a pronounced difference between homogeneous or microheterogeneous and macroporous gels with communicating pores. The achievement of optimum conditions for the correct determination of shear modulus was also analysed. (en)
Title
  • Rheological properties of homogeneous and heterogeneous poly(2-hydroxyethyl methacrylate) hydrogels
  • Rheological properties of homogeneous and heterogeneous poly(2-hydroxyethyl methacrylate) hydrogels (en)
skos:prefLabel
  • Rheological properties of homogeneous and heterogeneous poly(2-hydroxyethyl methacrylate) hydrogels
  • Rheological properties of homogeneous and heterogeneous poly(2-hydroxyethyl methacrylate) hydrogels (en)
skos:notation
  • RIV/61389013:_____/12:00374874!RIV12-AV0-61389013
http://linked.open...avai/riv/aktivita
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  • P(KAN200520804), Z(AV0Z40500505)
http://linked.open...iv/cisloPeriodika
  • 2
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  • 165541
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  • RIV/61389013:_____/12:00374874
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  • hydrogel; 2-hydroxyethyl methacrylate; phase separation (en)
http://linked.open.../riv/klicoveSlovo
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [446F3FDF016E]
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  • Polymer International
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  • 61
http://linked.open...iv/tvurceVysledku
  • Dušek, Karel
  • Dušková-Smrčková, Miroslava
  • Lapčíková, Monika
  • Karpushkin, Evgeny
  • Remmler, T.
http://linked.open...ain/vavai/riv/wos
  • 000298840000025
http://linked.open...n/vavai/riv/zamer
issn
  • 0959-8103
number of pages
http://bibframe.org/vocab/doi
  • 10.1002/pi.3194
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