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rdf:type
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Description
| - The oxidation of aniline with silver nitrate yielded a composite of two conducting components, polyaniline and silver. The acceleration with 1 mol% of p-phenylenediamine is needed for efficient synthesis. The product displayed metallic conductivity below 180 K and semiconductor type above this temperature. As the result, the conductivity was the same at 100 and 300 K. The oxidation of p-phenylenediamine alone with silver nitrate also produced a conducting composite having the conductivity of 1,750 S/cm despite the assumed nonconductivity of poly(p-phenylenediamine). The present study demonstrates that all oxidations proceeded also in frozen reaction mixtures at 24 °C, i.e., in the solid state.
- The oxidation of aniline with silver nitrate yielded a composite of two conducting components, polyaniline and silver. The acceleration with 1 mol% of p-phenylenediamine is needed for efficient synthesis. The product displayed metallic conductivity below 180 K and semiconductor type above this temperature. As the result, the conductivity was the same at 100 and 300 K. The oxidation of p-phenylenediamine alone with silver nitrate also produced a conducting composite having the conductivity of 1,750 S/cm despite the assumed nonconductivity of poly(p-phenylenediamine). The present study demonstrates that all oxidations proceeded also in frozen reaction mixtures at 24 °C, i.e., in the solid state. (en)
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Title
| - The preparation of conducting polyaniline-silver and poly(p-phenylenediamine)-silver nanocomposites in liquid and frozen reaction mixtures
- The preparation of conducting polyaniline-silver and poly(p-phenylenediamine)-silver nanocomposites in liquid and frozen reaction mixtures (en)
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skos:prefLabel
| - The preparation of conducting polyaniline-silver and poly(p-phenylenediamine)-silver nanocomposites in liquid and frozen reaction mixtures
- The preparation of conducting polyaniline-silver and poly(p-phenylenediamine)-silver nanocomposites in liquid and frozen reaction mixtures (en)
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skos:notation
| - RIV/61389013:_____/11:00367305!RIV12-AV0-61389013
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(LA09028), Z(AV0Z40500505), Z(MSM0021620834)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61389013:_____/11:00367305
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - polyaniline; composites; conducting polymer (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - DE - Spolková republika Německo
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Journal of Solid State Electrochemistry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
| |
http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
| |
http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Stejskal, Jaroslav
- Trchová, Miroslava
- Prokeš, J.
- Bober, Patrycja
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1007/s10008-011-1414-8
|