About: Exploitation of modern physical techniques in characterization of accelerated weathering processes in commodity polymers; ESRI, ATR FTIR and diffuse transmittance measurements     Goto   Sponge   NotDistinct   Permalink

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Description
  • Weathering of polymers comprises a large number of photooxidation processes triggered by environmental factors. It accounts for heterogeneous photodegradation that has negative impact on material properties of polymers. The degradation can be minimized by application of stabilizers, hindered amine stabilizers (HAS) in particular. We applied modern physical techniques that are able to bring unique information on the heterogeneity of the degradation process. Development of concentration profiles of nitroxides inside polymer plaques and concentrations of oxidation products on the surfaces and inside the plaques were determined by ESRI and by ATR FTIR, respectively. Diffuse optical transmission of the plaques was determined using spectrophotometer equipped with an integration sphere. Data determined in four commodity carbon chain polymers PP, PE, PS and Topas stabilized with secondary HAS Tinuvin 770 and with Tinuvin NOR 123 are compared.
  • Weathering of polymers comprises a large number of photooxidation processes triggered by environmental factors. It accounts for heterogeneous photodegradation that has negative impact on material properties of polymers. The degradation can be minimized by application of stabilizers, hindered amine stabilizers (HAS) in particular. We applied modern physical techniques that are able to bring unique information on the heterogeneity of the degradation process. Development of concentration profiles of nitroxides inside polymer plaques and concentrations of oxidation products on the surfaces and inside the plaques were determined by ESRI and by ATR FTIR, respectively. Diffuse optical transmission of the plaques was determined using spectrophotometer equipped with an integration sphere. Data determined in four commodity carbon chain polymers PP, PE, PS and Topas stabilized with secondary HAS Tinuvin 770 and with Tinuvin NOR 123 are compared. (en)
Title
  • Exploitation of modern physical techniques in characterization of accelerated weathering processes in commodity polymers; ESRI, ATR FTIR and diffuse transmittance measurements
  • Exploitation of modern physical techniques in characterization of accelerated weathering processes in commodity polymers; ESRI, ATR FTIR and diffuse transmittance measurements (en)
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  • Exploitation of modern physical techniques in characterization of accelerated weathering processes in commodity polymers; ESRI, ATR FTIR and diffuse transmittance measurements
  • Exploitation of modern physical techniques in characterization of accelerated weathering processes in commodity polymers; ESRI, ATR FTIR and diffuse transmittance measurements (en)
skos:notation
  • RIV/61389013:_____/11:00364739!RIV12-AV0-61389013
http://linked.open...avai/riv/aktivita
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  • P(IAA400500804), Z(AV0Z40500505)
http://linked.open...vai/riv/dodaniDat
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  • 198965
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  • RIV/61389013:_____/11:00364739
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  • commodity polymers; photodegradation; diffuse transmittance (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [F5C1151D9982]
http://linked.open...v/mistoKonaniAkce
  • Lisbon
http://linked.open...i/riv/mistoVydani
  • Pfinztal
http://linked.open...i/riv/nazevZdroje
  • Natural and Artificial Ageing of Polymers
http://linked.open...in/vavai/riv/obor
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http://linked.open...vavai/riv/projekt
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  • Michálková, Danuše
  • Pfleger, Jiří
  • Pilař, Jan
  • Šeděnková, Ivana
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
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  • Confederation of European Environmental Engineering Societies (CEEES) - Gesellschaft für Umweltsimulation GUS
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  • 978-3-9813136-2-8
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