About: Extraction and DFT study on the complexation of the cesium cation with dibenzo-21-crown-7     Goto   Sponge   NotDistinct   Permalink

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  • From extraction experiments and γ-activity measurements, the extraction constant corresponding to the equilibrium of cesium cation and picrate in the two-phase water-nitrobenzene system was evaluated as 4.4. Further, the stability constant of the studied complex in nitrobenzene saturated with water was calculated for a temperature of 25 °C: log beta = 6.3. Finally, by using quantum mechanical DFT calculations, the most probable structure of the resulting cationic complex species was solved.
  • From extraction experiments and γ-activity measurements, the extraction constant corresponding to the equilibrium of cesium cation and picrate in the two-phase water-nitrobenzene system was evaluated as 4.4. Further, the stability constant of the studied complex in nitrobenzene saturated with water was calculated for a temperature of 25 °C: log beta = 6.3. Finally, by using quantum mechanical DFT calculations, the most probable structure of the resulting cationic complex species was solved. (en)
Title
  • Extraction and DFT study on the complexation of the cesium cation with dibenzo-21-crown-7
  • Extraction and DFT study on the complexation of the cesium cation with dibenzo-21-crown-7 (en)
skos:prefLabel
  • Extraction and DFT study on the complexation of the cesium cation with dibenzo-21-crown-7
  • Extraction and DFT study on the complexation of the cesium cation with dibenzo-21-crown-7 (en)
skos:notation
  • RIV/61389013:_____/11:00361472!RIV12-AV0-61389013
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GAP205/10/2280), S, Z(AV0Z40500505), Z(MSM4977751303)
http://linked.open...iv/cisloPeriodika
  • 3
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 199096
http://linked.open...ai/riv/idVysledku
  • RIV/61389013:_____/11:00361472
http://linked.open...riv/jazykVysledku
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  • cesium dibenzo-21-crown-7; nitrobenzene; stability constant (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • HU - Maďarsko
http://linked.open...ontrolniKodProRIV
  • [D53E72608476]
http://linked.open...i/riv/nazevZdroje
  • Journal of Radioanalytical and Nuclear Chemistry
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http://linked.open...v/svazekPeriodika
  • 289
http://linked.open...iv/tvurceVysledku
  • Makrlík, E.
  • Toman, Petr
  • Vaňura, P.
http://linked.open...ain/vavai/riv/wos
  • 000293029200003
http://linked.open...n/vavai/riv/zamer
issn
  • 0236-5731
number of pages
http://bibframe.org/vocab/doi
  • 10.1007/s10967-011-1123-x
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