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Description
| - To determine the influence of particle size on the specific surface area of hypercrosslinked poly(styrene-co-divinylbenzene) (PS) microspheres. Suspension and dispersion polymerization were chosen for their preparation. Dispersion copolymerization of styrene and divinylbenzene (DVB) in ethanol was stabilized by (hydroxypropyl)cellulose (HPC) and initiated with dibenzoyl peroxide . Monodisperse 1.4-µm microspheres were prepared in the presence of 3.6 wt% HPC. Microspheres were chloromethylated with chloromethyl methyl ether , chloromethyl ethyl ether or chloromethyl octyl ether to investigate the effect of the chloromethylation agent on the specific surface area of microspheres. Chloromethylated microspheres were hypercrosslinked in 1,2-dichloroethane (DCE) with SnCl4. The effects of the (DVB) and DCE/microsphere ratio on properties of the product were studied. Characterization of porous structure were done by dynamic desorption of nitrogen, cyclohexane regain and mercury porosimetry.
- To determine the influence of particle size on the specific surface area of hypercrosslinked poly(styrene-co-divinylbenzene) (PS) microspheres. Suspension and dispersion polymerization were chosen for their preparation. Dispersion copolymerization of styrene and divinylbenzene (DVB) in ethanol was stabilized by (hydroxypropyl)cellulose (HPC) and initiated with dibenzoyl peroxide . Monodisperse 1.4-µm microspheres were prepared in the presence of 3.6 wt% HPC. Microspheres were chloromethylated with chloromethyl methyl ether , chloromethyl ethyl ether or chloromethyl octyl ether to investigate the effect of the chloromethylation agent on the specific surface area of microspheres. Chloromethylated microspheres were hypercrosslinked in 1,2-dichloroethane (DCE) with SnCl4. The effects of the (DVB) and DCE/microsphere ratio on properties of the product were studied. Characterization of porous structure were done by dynamic desorption of nitrogen, cyclohexane regain and mercury porosimetry. (en)
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Title
| - Hypercrosslinked polystyrene microspheres by suspension and dispersion polymerization
- Hypercrosslinked polystyrene microspheres by suspension and dispersion polymerization (en)
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skos:prefLabel
| - Hypercrosslinked polystyrene microspheres by suspension and dispersion polymerization
- Hypercrosslinked polystyrene microspheres by suspension and dispersion polymerization (en)
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skos:notation
| - RIV/61389013:_____/11:00360930!RIV12-AV0-61389013
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(2B06053), P(GA203/09/0857), P(GAP503/10/0664), Z(AV0Z40500505)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61389013:_____/11:00360930
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - polystyrene; microspheres; hypercrosslinked (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Horák, Daniel
- Šálek, Petr
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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