About: Structures and characterization of [Zn(n-chlorosalicylato)2(N-methylnicotinamide)2(H2O)2] (n = 4 or 5) ligand isomers

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About: Structures and characterization of [Zn(n-chlorosalicylato)2(N-methylnicotinamide)2(H2O)2] (n = 4 or 5) ligand isomers Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Two ligand isomers [Zn{4-ClC6H3-2-(OH)COO}(2)(Menia)(2)(H2O)(2)] (I) and [Zn{5-ClC6H3-2-(OH)COO}(2)(Menia)(2)(H2O)(2)] (II) (Menia = N-methylnicotinamide) were prepared and characterized by elemental analysis, IR spectroscopy and thermal analysis. Also X-ray crystal structures of complexes (I) and (II) were determined. They both crystallize in the triclinic space group P (1) over bar, differing in cell parameters. The molecular structure of both isomers is monomeric. Each Zn(II) atom is hexacoordinated by three pairs of unidentate ligands in trans-positions (ZnO4N2). The 5-Clsal complex is somewhat less distorted than 4-Clsal complex (Cl-sal = chlorosalicylate). The structural data are compared with those found in a similar compound [Zn(RCOO)(2)(NL)(2)(H2O)(2)]. Two ligand isomers [Zn{4-ClC6H3-2-(OH)COO}(2)(Menia)(2)(H2O)(2)] (I) and [Zn{5-ClC6H3-2-(OH)COO}(2)(Menia)(2)(H2O)(2)] (II) (Menia = N-methylnicotinamide) were prepared and characterized by elemental analysis, IR spectroscopy and thermal analysis. Also X-ray crystal structures of complexes (I) and (II) were determined. They both crystallize in the triclinic space group P (1) over bar, differing in cell parameters. The molecular structure of both isomers is monomeric. Each Zn(II) atom is hexacoordinated by three pairs of unidentate ligands in trans-positions (ZnO4N2). The 5-Clsal complex is somewhat less distorted than 4-Clsal complex (Cl-sal = chlorosalicylate). The structural data are compared with those found in a similar compound [Zn(RCOO)(2)(NL)(2)(H2O)(2)]. (en)
Title	Structures and characterization of [Zn(n-chlorosalicylato)2(N-methylnicotinamide)2(H2O)2] (n = 4 or 5) ligand isomers Structures and characterization of [Zn(n-chlorosalicylato)2(N-methylnicotinamide)2(H2O)2] (n = 4 or 5) ligand isomers (en)
skos:prefLabel	Structures and characterization of [Zn(n-chlorosalicylato)2(N-methylnicotinamide)2(H2O)2] (n = 4 or 5) ligand isomers Structures and characterization of [Zn(n-chlorosalicylato)2(N-methylnicotinamide)2(H2O)2] (n = 4 or 5) ligand isomers (en)
skos:notation	RIV/61389013:_____/11:00358731!RIV12-AV0-61389013
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(AV0Z40500505)
http://linked.open...iv/cisloPeriodika	4
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Kovářová, Jana
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav makromolekulární chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	232829
http://linked.open...ai/riv/idVysledku	RIV/61389013:_____/11:00358731
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	structure; chlorosalicylate; zinc(II) (en)
http://linked.open.../riv/klicoveSlovo	chlorosalicylate zinc(II) structure
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[C86B4A4402DC]
http://linked.open...i/riv/nazevZdroje	Journal of Chemical Crystallography
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	41
http://linked.open...iv/tvurceVysledku	Kovářová, Jana Györyová, K. Bujdošová, Z. Koman, M. Melník, M.
http://linked.open...ain/vavai/riv/wos	000288178600002
http://linked.open...n/vavai/riv/zamer	Progresivní makromolekulární materiály a supramolekulární systémy: syntéza a studium vlastností, jevů a možností využití pro speciální aplikace a moderní technologie
issn	1074-1542
number of pages	6 (xsd:int)
http://bibframe.org/vocab/doi	10.1007/s10870-010-9898-0

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