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  • We prepared cycloolefin copolymer (COC)/fumed silica nanocomposites by melt compounding in order to study the effect of the filler dimensions (filler surface area) on the physical properties, with particular attention to their thermal, mechanical, and optical behaviors. Thermogravimetric analysis revealed a positive contribution of silica nanoparticles to the thermal degradation resistance of COC. Dynamic mechanical thermal analysis and quasi-static tensile tests of the nanocomposites evidenced a slight stiffening effect, proportional to the nanofiller surface area, without any reduction in the fracture toughness. The positive effect of the nanoparticles on the viscoelastic, creep and fracture behavior was related to the uniform dispersion of silica aggregates in the matrix. Ultraviolet–visible spectrometry measurements evidenced that the original transparency of neat COC was practically maintained after the addition of silica nanoparticles.
  • We prepared cycloolefin copolymer (COC)/fumed silica nanocomposites by melt compounding in order to study the effect of the filler dimensions (filler surface area) on the physical properties, with particular attention to their thermal, mechanical, and optical behaviors. Thermogravimetric analysis revealed a positive contribution of silica nanoparticles to the thermal degradation resistance of COC. Dynamic mechanical thermal analysis and quasi-static tensile tests of the nanocomposites evidenced a slight stiffening effect, proportional to the nanofiller surface area, without any reduction in the fracture toughness. The positive effect of the nanoparticles on the viscoelastic, creep and fracture behavior was related to the uniform dispersion of silica aggregates in the matrix. Ultraviolet–visible spectrometry measurements evidenced that the original transparency of neat COC was practically maintained after the addition of silica nanoparticles. (en)
Title
  • Cycloolefin copolymer/fumed silica nanocomposites
  • Cycloolefin copolymer/fumed silica nanocomposites (en)
skos:prefLabel
  • Cycloolefin copolymer/fumed silica nanocomposites
  • Cycloolefin copolymer/fumed silica nanocomposites (en)
skos:notation
  • RIV/61389013:_____/11:00351366!RIV11-GA0-61389013
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA106/09/1348), Z(AV0Z40500505)
http://linked.open...iv/cisloPeriodika
  • 6
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 192592
http://linked.open...ai/riv/idVysledku
  • RIV/61389013:_____/11:00351366
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • creep; nanocomposites; polyolefins (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [AC429BFEDD42]
http://linked.open...i/riv/nazevZdroje
  • Journal of Applied Polymer Science
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 119
http://linked.open...iv/tvurceVysledku
  • Šlouf, Miroslav
  • Dorigato, A.
  • Fambri, L.
  • Kolařík, Jan
  • Pegoretti, A.
http://linked.open...ain/vavai/riv/wos
  • 000285312800031
http://linked.open...n/vavai/riv/zamer
issn
  • 0021-8995
number of pages
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