About: Improvement in carrier mobility and photovoltaic performance through random distribution of segments of linear and branched side chains     Goto   Sponge   NotDistinct   Permalink

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  • The random distribution of segments of linear octyloxy side chains and of branched 2-ethylhexyloxy side chains, on the backbone of anthracene containing poly(p-phenylene-ethynylene)-alt-poly(p-phenylene-vinylene) (PPE-PPV) has resulted in a side chain based statistical copolymer, denoted AnE-PVstat, showing optimized features as compared to the well defined homologues whose constitutional units are incorporated into its backbone. Electric field independent charge carrier mobility (µhole) for AnE-PVstat as demonstrated by CELIV and OFET measurements is predominantly an intrachain process and less an interchain one, which is in line with past photoconductivity results from PPE-PPV based materials. The present side chain distribution favors efficient solar cell active layer phase separation. As a result, a smaller amount of PC60BM is needed to achieve relatively high energy conversion efficiencies above 3%.
  • The random distribution of segments of linear octyloxy side chains and of branched 2-ethylhexyloxy side chains, on the backbone of anthracene containing poly(p-phenylene-ethynylene)-alt-poly(p-phenylene-vinylene) (PPE-PPV) has resulted in a side chain based statistical copolymer, denoted AnE-PVstat, showing optimized features as compared to the well defined homologues whose constitutional units are incorporated into its backbone. Electric field independent charge carrier mobility (µhole) for AnE-PVstat as demonstrated by CELIV and OFET measurements is predominantly an intrachain process and less an interchain one, which is in line with past photoconductivity results from PPE-PPV based materials. The present side chain distribution favors efficient solar cell active layer phase separation. As a result, a smaller amount of PC60BM is needed to achieve relatively high energy conversion efficiencies above 3%. (en)
Title
  • Improvement in carrier mobility and photovoltaic performance through random distribution of segments of linear and branched side chains
  • Improvement in carrier mobility and photovoltaic performance through random distribution of segments of linear and branched side chains (en)
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  • Improvement in carrier mobility and photovoltaic performance through random distribution of segments of linear and branched side chains
  • Improvement in carrier mobility and photovoltaic performance through random distribution of segments of linear and branched side chains (en)
skos:notation
  • RIV/61389013:_____/10:00349040!RIV11-MSM-61389013
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(1M06031), Z(AV0Z40500505)
http://linked.open...iv/cisloPeriodika
  • 43
http://linked.open...vai/riv/dodaniDat
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  • 263180
http://linked.open...ai/riv/idVysledku
  • RIV/61389013:_____/10:00349040
http://linked.open...riv/jazykVysledku
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  • poly(p-phenylene-ethynylene)-alt-poly(p-phenylene-vinylene); solar cells; charge carrier mobility (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [E317E7A44A26]
http://linked.open...i/riv/nazevZdroje
  • Journal of Materials Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 20
http://linked.open...iv/tvurceVysledku
  • Cimrová, Věra
  • Adam, G.
  • Birckner, E.
  • Egbe, D. A. M.
  • Hoppe, H.
  • Sariciftci, N. S.
  • Pivrikas, A.
  • Ramil, A. M.
http://linked.open...ain/vavai/riv/wos
  • 000283603000021
http://linked.open...n/vavai/riv/zamer
issn
  • 0959-9428
number of pages
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