About: Experimental evidence, stability, and the most probable structure of protonated p-tert-butylcalix[4]arenetetrakis (N,N-dimethylacetamide)

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About: Experimental evidence, stability, and the most probable structure of protonated p-tert-butylcalix[4]arenetetrakis (N,N-dimethylacetamide) Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	From extraction experiments and gamma-activity measurements, the extraction constant corresponding to the equilibrium H3O+(aq) + 1.Na+(nb) equil. 1.H3O+ (nb) + Na+ (aq) taking place in the two-phase water-nitrobenzene system (1: p-tert-butylcalix[4] arenetetrakis(N,N-dimethylacetamide)) was evaluated as -0.1 +/- 0.1. By using quantum mechanical DFT calculations, the most probable structure of the 1.H3O+ cationic complex species was derived. From extraction experiments and gamma-activity measurements, the extraction constant corresponding to the equilibrium H3O+(aq) + 1.Na+(nb) equil. 1.H3O+ (nb) + Na+ (aq) taking place in the two-phase water-nitrobenzene system (1: p-tert-butylcalix[4] arenetetrakis(N,N-dimethylacetamide)) was evaluated as -0.1 +/- 0.1. By using quantum mechanical DFT calculations, the most probable structure of the 1.H3O+ cationic complex species was derived. (en)
Title	Experimental evidence, stability, and the most probable structure of protonated p-tert-butylcalix[4]arenetetrakis (N,N-dimethylacetamide) Experimental evidence, stability, and the most probable structure of protonated p-tert-butylcalix[4]arenetetrakis (N,N-dimethylacetamide) (en)
skos:prefLabel	Experimental evidence, stability, and the most probable structure of protonated p-tert-butylcalix[4]arenetetrakis (N,N-dimethylacetamide) Experimental evidence, stability, and the most probable structure of protonated p-tert-butylcalix[4]arenetetrakis (N,N-dimethylacetamide) (en)
skos:notation	RIV/61389013:_____/09:00330562!RIV10-AV0-61389013
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(1ET400500402), Z(AV0Z40500505), Z(MSM4977751303), Z(MSM6046137307)
http://linked.open...iv/cisloPeriodika	10
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Dybal, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav makromolekulární chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	314224
http://linked.open...ai/riv/idVysledku	RIV/61389013:_____/09:00330562
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	calixarenes; macrocycles; protonation (en)
http://linked.open.../riv/klicoveSlovo	macrocycles protonation calixarenes
http://linked.open...odStatuVydavatele	AT - Rakouská republika
http://linked.open...ontrolniKodProRIV	[1329768F38E0]
http://linked.open...i/riv/nazevZdroje	Monatshefte fur Chemie
http://linked.open...in/vavai/riv/obor	CD
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Computer modelling of chmical structures for the design of macromolecular systems with new biological, mechanical and electronic properties
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	140
http://linked.open...iv/tvurceVysledku	Dybal, Jiří Makrlík, E. Vaňura, P. Budka, J.
http://linked.open...ain/vavai/riv/wos	000270185100005
http://linked.open...n/vavai/riv/zamer	Progresivní makromolekulární materiály a supramolekulární systémy: syntéza a studium vlastností, jevů a možností využití pro speciální aplikace a moderní technologie Predikce poruch heterogenních materiálů, komponent mechanických a biomechanických systémů. Physico-chemical methods of analysis and characterization of chemical systems and biosystems
issn	0026-9247
number of pages	4 (xsd:int)

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