About: Solvent-controlled ring size in double C,N-chelated stannoxane

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The stannylene (L-CN)(2)Sn where L-CN is a chelating ligand (2-(N,N-dimethylaminomethyl)phenyl-) was oxidized by an excess of oxygen, nitrous oxide, or TEMPO free radical, giving dimeric stannoxane [(L-CN)(2)Sn](2)(mu-O)(2) in dynamic equilibrium with its monomeric form in solution. In the solid state, an unusual tetraoxatetrastannacycle cyclo-[(L-CN)(2)SnO](4) can be crystallized from diethyl ether and the trioxatristannacyclic complex of formula cyclo-[(L-CN)(2)SnO](3) from the hexane solution. The stannylene (L-CN)(2)Sn where L-CN is a chelating ligand (2-(N,N-dimethylaminomethyl)phenyl-) was oxidized by an excess of oxygen, nitrous oxide, or TEMPO free radical, giving dimeric stannoxane [(L-CN)(2)Sn](2)(mu-O)(2) in dynamic equilibrium with its monomeric form in solution. In the solid state, an unusual tetraoxatetrastannacycle cyclo-[(L-CN)(2)SnO](4) can be crystallized from diethyl ether and the trioxatristannacyclic complex of formula cyclo-[(L-CN)(2)SnO](3) from the hexane solution. (en) Sloučeniny typu (L-CN)(2)Sn kde L-CN je ligand (2-(N,N-dimethylaminomethyl)phenyl-) byly oxidovány kyslíkem nebo TEPO radikálem za vzniku dimerů typu [(L-CN)(2)Sn](2)(mu-O)(2) jež se v roztoku nachází v dynamické rovnováze s monomerní formou. Neobvyklé tetramerní a trimerní formy byly získány krystalizací z roztoků diethyl etheru resp. hexanu. (cs)
Title	Solvent-controlled ring size in double C,N-chelated stannoxane Rozpouštědlem řízená velikost cyklu u C,N-chelatovaných stanoxanů (cs) Solvent-controlled ring size in double C,N-chelated stannoxane (en)
skos:prefLabel	Solvent-controlled ring size in double C,N-chelated stannoxane Rozpouštědlem řízená velikost cyklu u C,N-chelatovaných stanoxanů (cs) Solvent-controlled ring size in double C,N-chelated stannoxane (en)
skos:notation	RIV/61389013:_____/08:00316901!RIV09-AV0-61389013
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/07/0468), P(KJB401550802), P(LC523), Z(AV0Z40500505), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika	20
http://linked.open...vai/riv/dodaniDat	2009
http://linked.open...aciTvurceVysledku	Brus, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav makromolekulární chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	395854
http://linked.open...ai/riv/idVysledku	RIV/61389013:_____/08:00316901
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	compact effective potentials; molecular diorganotin oxide (en)
http://linked.open.../riv/klicoveSlovo	compact effective potentials molecular diorganotin oxide
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[312BDD7381B5]
http://linked.open...i/riv/nazevZdroje	Organometallics
http://linked.open...in/vavai/riv/obor	CD
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Perspective inorganic materials Study of properties and the use of C,N- and Y,C,Y-chelated organometallic compounds LOW VALENT GROUP 14 ORGANOMETALLIC COMPOUNDS, SYNTHESIS, STRUCTURE AND REACTIVITY
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	27
http://linked.open...iv/tvurceVysledku	Padělková, Z. Růžička, A. Brus, Jiří Černošek, Z. Nechaev, M.
http://linked.open...ain/vavai/riv/wos	000259988800017
http://linked.open...n/vavai/riv/zamer	Progresivní makromolekulární materiály a supramolekulární systémy: syntéza a studium vlastností, jevů a možností využití pro speciální aplikace a moderní technologie Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures
issn	0276-7333
number of pages	6 (xsd:int)

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