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Description
  • Je popsána nová chemická modifikace kapalného polybutadienu radikálovou adicí modelových aldehydů (butanalu a hexanalu) na visící vinyly polymeru. Bylo prokázáno, že redoxní systém na bázi dibenzoylperoxidu a N,N-dimethylanilinu iniciuje hydroacylaci účinněji než termální rozklad 2,2-azobis(2-methylpropannitrilu), neboť dává vyšší konverze (vyšší obsah hydroacylovaných monomerních jednotek). (cs)
  • A new chemical modification of liquid polybutadiene by radical addition of model aldehydes (butanal and hexanal) onto pending vinyls of the polymer is described. The dibenzoyl peroxide/N,N-dimethylaniline redox system was shown to initiate the hydroacylation more efficiently than the thermal decomposition of 2,2-azobis(2-methylpropanenitrile) because it gives higher conversions (a higher content of hydroacylated monomer units).
  • A new chemical modification of liquid polybutadiene by radical addition of model aldehydes (butanal and hexanal) onto pending vinyls of the polymer is described. The dibenzoyl peroxide/N,N-dimethylaniline redox system was shown to initiate the hydroacylation more efficiently than the thermal decomposition of 2,2-azobis(2-methylpropanenitrile) because it gives higher conversions (a higher content of hydroacylated monomer units). (en)
Title
  • A new chemical modification of liquid polybutadienes: Radical addition of aliphatic aldehydes onto pending vinyl groups
  • A new chemical modification of liquid polybutadienes: Radical addition of aliphatic aldehydes onto pending vinyl groups (en)
  • Nová chemická modifikace kapalných polybutadienů: Radikálová adice alifatických aldehydů na visící vinylové skupiny (cs)
skos:prefLabel
  • A new chemical modification of liquid polybutadienes: Radical addition of aliphatic aldehydes onto pending vinyl groups
  • A new chemical modification of liquid polybutadienes: Radical addition of aliphatic aldehydes onto pending vinyl groups (en)
  • Nová chemická modifikace kapalných polybutadienů: Radikálová adice alifatických aldehydů na visící vinylové skupiny (cs)
skos:notation
  • RIV/61389013:_____/08:00312476!RIV09-AV0-61389013
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/07/0987), Z(AV0Z40500505)
http://linked.open...iv/cisloPeriodika
  • 12
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 354288
http://linked.open...ai/riv/idVysledku
  • RIV/61389013:_____/08:00312476
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • functionalization of polymers; gel permeation chromatography; NMR; polybutadiene (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [F12E6C500EF8]
http://linked.open...i/riv/nazevZdroje
  • Journal of Polymer Science. Part A - Polymer Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 46
http://linked.open...iv/tvurceVysledku
  • Hrubý, Martin
  • Netopilík, Miloš
  • Spěváček, Jiří
  • Podešva, Jiří
  • Hrdličková, Miluše
http://linked.open...ain/vavai/riv/wos
  • 000256643500005
http://linked.open...n/vavai/riv/zamer
issn
  • 0887-624X
number of pages
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