About: Back-biting termination in methyl methacrylate/tert-butyl acrylate anionic block copolymerization     Goto   Sponge   NotDistinct   Permalink

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Description
  • Byl izolován produkt samovolné terminace živého PMMA řetězce po adici jedné nebo dvou jednotek t-BuA při aniontové kopolymerizaci MMA/t-BuA a charakterizován pomocí SEC, UV, FT-IR a Ramanovou a NMR spektroskopií. Tento produkt se objevuje jako nízkomolekulární pík v SEC eluogramu výsledného blokového kopolymeru, absorbuje v UV oblasti při 260 nm a jeho retenční čas odpovídá retenčnímu času PMMA bloku. V práci jsou uvedeny experimentální důkazy back-biting reakce při cross-iniciaci t-BuA polymerizace živým PMMA. (cs)
  • The product of spontaneous termination formed after addition of one or two t-BuA units onto living PMMA chains in theMMA/t-BuA block copolymerization was isolated and characterized by SEC, UV, FT-IR, Raman and NMR spectroscopy. It appears as a low-molecular-weight peak in SEC eluograms of the copolymers, absorbing at 260 nm; its retention time corresponds to that of the PMMA block. Experimental support of a back-biting reaction at the link between PMMA and Pt-BuA blocks is presented.
  • The product of spontaneous termination formed after addition of one or two t-BuA units onto living PMMA chains in theMMA/t-BuA block copolymerization was isolated and characterized by SEC, UV, FT-IR, Raman and NMR spectroscopy. It appears as a low-molecular-weight peak in SEC eluograms of the copolymers, absorbing at 260 nm; its retention time corresponds to that of the PMMA block. Experimental support of a back-biting reaction at the link between PMMA and Pt-BuA blocks is presented. (en)
Title
  • Back-biting termination in methyl methacrylate/tert-butyl acrylate anionic block copolymerization
  • Back-biting termination in methyl methacrylate/tert-butyl acrylate anionic block copolymerization (en)
  • Autoterminační reakce při aniontové blokové kopolymerizaci methyl methaktylátu a tert-butyl akrylátu (cs)
skos:prefLabel
  • Back-biting termination in methyl methacrylate/tert-butyl acrylate anionic block copolymerization
  • Back-biting termination in methyl methacrylate/tert-butyl acrylate anionic block copolymerization (en)
  • Autoterminační reakce při aniontové blokové kopolymerizaci methyl methaktylátu a tert-butyl akrylátu (cs)
skos:notation
  • RIV/61389013:_____/08:00310895!RIV09-AV0-61389013
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(AV0Z40500505)
http://linked.open...iv/cisloPeriodika
  • 16
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 357529
http://linked.open...ai/riv/idVysledku
  • RIV/61389013:_____/08:00310895
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • acrylates; anionic polymerization; spontaneous termination (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [9BA2CA93A6C7]
http://linked.open...i/riv/nazevZdroje
  • Macromolecular Chemistry and Physics
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 209
http://linked.open...iv/tvurceVysledku
  • Dybal, Jiří
  • Janata, Miroslav
  • Kříž, Jaroslav
  • Vlček, Petr
  • Čadová, Eva
  • Toman, Luděk
http://linked.open...ain/vavai/riv/wos
  • 000258907100002
http://linked.open...n/vavai/riv/zamer
issn
  • 1022-1352
number of pages
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