About: Cooperative hydrogen bonds of macromolecules. 3. A model study of the proximity effect     Goto   Sponge   NotDistinct   Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

AttributesValues
rdf:type
Description
  • Proximitní efekt v kooperativních vodíkových vazbách byl prokázán v modelové studii přechodné vazby kyseliny glutarové a adipové na poly(4-vinylpyridin). Důkaz byl jak experimentální, používající PFG NMR a NMR relaxace, tak teoretický, užívající kvantové DFT B3LYP/6-31G(d) výpočty. Bylo ukázáno, že pro každou přechodně vázanou COOH skupinu podmíněná pravděpodobnost, že druhá COOH skupina bude vázána též, je 0.7 pro kyselinu glutarovou a 0.63 pro kyselinu adipovou. Výpočty ukázaly, že efekt je entropický. (cs)
  • The proximity effect in cooperative hydrogen bonds was proved in a model study of transient binding glutaric and adipic acids to poly(4-vinylpyridine). The proof was both experimental, using PFG NMR and NMR relaxation, and theoretical, using quantum DFT B3LYP/6-31G(d) calculations. It was shown that for every transiently bound COOH group the conditional probability of the second COOH group being also bound is 0.7 and 0.63 for glutaric acid and adipic acid, respectively. The calculations show that the effect is entropic.
  • The proximity effect in cooperative hydrogen bonds was proved in a model study of transient binding glutaric and adipic acids to poly(4-vinylpyridine). The proof was both experimental, using PFG NMR and NMR relaxation, and theoretical, using quantum DFT B3LYP/6-31G(d) calculations. It was shown that for every transiently bound COOH group the conditional probability of the second COOH group being also bound is 0.7 and 0.63 for glutaric acid and adipic acid, respectively. The calculations show that the effect is entropic. (en)
Title
  • Cooperative hydrogen bonds of macromolecules. 3. A model study of the proximity effect
  • Kooperativní vodíkové vazby makromolekul. 3. Modelová studie proximitního efektu (cs)
  • Cooperative hydrogen bonds of macromolecules. 3. A model study of the proximity effect (en)
skos:prefLabel
  • Cooperative hydrogen bonds of macromolecules. 3. A model study of the proximity effect
  • Kooperativní vodíkové vazby makromolekul. 3. Modelová studie proximitního efektu (cs)
  • Cooperative hydrogen bonds of macromolecules. 3. A model study of the proximity effect (en)
skos:notation
  • RIV/61389013:_____/07:00082963!RIV07-AV0-61389013
http://linked.open.../vavai/riv/strany
  • 6118;6126
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(1ET400500402), P(IAA400500604), Z(AV0Z40500505)
http://linked.open...iv/cisloPeriodika
  • 22
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 415081
http://linked.open...ai/riv/idVysledku
  • RIV/61389013:_____/07:00082963
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • cooperativity; cooperative hydrogen bonds; NMR; DFT (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [463C5FB3C41B]
http://linked.open...i/riv/nazevZdroje
  • Journal of Physical Chemistry B
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 111
http://linked.open...iv/tvurceVysledku
  • Dybal, Jiří
  • Kříž, Jaroslav
http://linked.open...n/vavai/riv/zamer
issn
  • 1520-6106
number of pages
Faceted Search & Find service v1.16.118 as of Jun 21 2024


Alternative Linked Data Documents: ODE     Content Formats:   [cxml] [csv]     RDF   [text] [turtle] [ld+json] [rdf+json] [rdf+xml]     ODATA   [atom+xml] [odata+json]     Microdata   [microdata+json] [html]    About   
This material is Open Knowledge   W3C Semantic Web Technology [RDF Data] Valid XHTML + RDFa
OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 70 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software