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  • Flexible polyurethane foam scrap was chemically decomposed via glycolysis. Optimal reaction conditions for glycolysis were determined: temperature, 2208C, polyurethane/glycol ratio, 1:1; reaction time, 2.5 hr; diethylene glycol or dipropylene glycol as reagents. Two types of polyurethane scrap were tested; both gave the recycled polyols having the same properties, which is advantageous for possible applications on a commercial scale. A mixture of the virgin and recycled polyols (up to 36 wt%) was used to manufacture rigid polyurethane foams. No undesirable influence of the recyclates on process parameters (cream time, gel time) was found. The end-use properties of the rigid foams were practically the same in the whole range of tested concentrations of recyclates. A fine cellular structure of all tested foams was found.
  • Flexible polyurethane foam scrap was chemically decomposed via glycolysis. Optimal reaction conditions for glycolysis were determined: temperature, 2208C, polyurethane/glycol ratio, 1:1; reaction time, 2.5 hr; diethylene glycol or dipropylene glycol as reagents. Two types of polyurethane scrap were tested; both gave the recycled polyols having the same properties, which is advantageous for possible applications on a commercial scale. A mixture of the virgin and recycled polyols (up to 36 wt%) was used to manufacture rigid polyurethane foams. No undesirable influence of the recyclates on process parameters (cream time, gel time) was found. The end-use properties of the rigid foams were practically the same in the whole range of tested concentrations of recyclates. A fine cellular structure of all tested foams was found. (en)
  • Odpadní měkké polyurethanová pěna byla podrobena glykolytickému rozkladu. Byly stanoveny optimální podmínky glykolýzy: teplota 220°C, polyurethan/glykol hm. poměr 1/1, reakční čas 2,5 h, diethylenglykol nebo dipropylenglykol jako reagenty. Byly odzkoušeny dva typy polyurethanového odpadu a z obou lze získat recyklované polyoly, které mají shodné vlastnosti, což je výhodné z hlediska jejich možné aplikace v průmyslovém měřítku. Směs panenského a recyklovaného polyolu (do 36 hm.%) se použila pro přípravu tvrdých polyurethanových pěn. Nebyl pozorován žádný nežádoucí vliv recyklátu na procesní parametry (čas do začátku vypěňování, čas gelace). Koncové vlastnosti tvrdých pěn byly prakticky shodné v celém testovaném koncentračním rozsahu přidávaných recyklátů. Struktura všech testovaných pěn obsahovala dostatečně jemné buňky. (cs)
Title
  • Glycolysis of flexible polyurethane foam in recycling of car seats
  • Glycolysis of flexible polyurethane foam in recycling of car seats (en)
  • Glykolýza měkké polyurethanové pěny při recyklaci autosedaček (cs)
skos:prefLabel
  • Glycolysis of flexible polyurethane foam in recycling of car seats
  • Glycolysis of flexible polyurethane foam in recycling of car seats (en)
  • Glykolýza měkké polyurethanové pěny při recyklaci autosedaček (cs)
skos:notation
  • RIV/61389013:_____/07:#0000008!RIV08-MZP-61389013
http://linked.open.../vavai/riv/strany
  • 149;156
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(SL/7/26/05), Z(AV0Z40500505)
http://linked.open...iv/cisloPeriodika
  • 18
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 423501
http://linked.open...ai/riv/idVysledku
  • RIV/61389013:_____/07:#0000008
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • polyurethanes; foams; recycling; glycolysis; degradation (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [71FBA0DD619E]
http://linked.open...i/riv/nazevZdroje
  • Polymers for Advanced Technologies
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 18
http://linked.open...iv/tvurceVysledku
  • Beneš, Hynek
http://linked.open...n/vavai/riv/zamer
issn
  • 1099-1581
number of pages
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