About: Double-C-N-chelated tri- and diorganotin(IV) fluorides

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Čtyři různé metody přípravy byly použity k fluoraci pěti různých sloučenin (LCN)2SnPhCl (1), (LCN) 2SnCl 2 (2), (LCN) 2SnBr 2 (3), (LCN) 2SnI 2 (4) a LCNSnPhCl 2 (5), kde LCN je (2-[(CH 3) 2NCH 2]C 6H 4). Jsou diskutovány různé mechanismy a výtěžky jednotlivých reakcí s ohledem na použité výchozí sloučeniny a výsledné produkty. (cs) Attempts to fluorinate the compounds (LCN)2SnPhCl (1), (LCN)2SnCl2 (2), (LCN)2SnBr2 (3), (LCN)2SnI2 (4) and LCNSnPhCl2 (5), where LCN is (2-[(CH3)2NCH2]C6H4), were made by four different methods. The fluorinated monomeric five-coordinated analogue of 1 was made by fluorination of 1 with KF/18-crown-6 ether and by metathetical fluorination with 10 (LCNSnBu2F). The fluorinated monomeric six-coordinated analogue ((LCN)2SnF2 (7)) of diorganotin compounds 2–4 was made easily by all methods used in adequate yield. The fluorination of 5 by all methods did not lead to the monomeric product and phenyl group migrations were observed during the course of these reactions. Attempts to fluorinate the compounds (LCN)2SnPhCl (1), (LCN)2SnCl2 (2), (LCN)2SnBr2 (3), (LCN)2SnI2 (4) and LCNSnPhCl2 (5), where LCN is (2-[(CH3)2NCH2]C6H4), were made by four different methods. The fluorinated monomeric five-coordinated analogue of 1 was made by fluorination of 1 with KF/18-crown-6 ether and by metathetical fluorination with 10 (LCNSnBu2F). The fluorinated monomeric six-coordinated analogue ((LCN)2SnF2 (7)) of diorganotin compounds 2–4 was made easily by all methods used in adequate yield. The fluorination of 5 by all methods did not lead to the monomeric product and phenyl group migrations were observed during the course of these reactions. (en)
Title	Double-C-N-chelated tri- and diorganotin(IV) fluorides Double-C-N-chelated tri- and diorganotin(IV) fluorides (en) Dvojitě chelatované tri- a diorganociničité fluoridy (cs)
skos:prefLabel	Double-C-N-chelated tri- and diorganotin(IV) fluorides Double-C-N-chelated tri- and diorganotin(IV) fluorides (en) Dvojitě chelatované tri- a diorganociničité fluoridy (cs)
skos:notation	RIV/61389013:_____/05:00029540!RIV06-AV0-61389013
http://linked.open.../vavai/riv/strany	1531;1538
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/04/0223), P(GP203/02/D169), P(LC523), Z(AV0Z40500505), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika	11-12
http://linked.open...vai/riv/dodaniDat	2006
http://linked.open...aciTvurceVysledku	Brus, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav makromolekulární chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	518708
http://linked.open...ai/riv/idVysledku	RIV/61389013:_____/05:00029540
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	organotin(IV) compounds; fluoride; C,N-ligand (en)
http://linked.open.../riv/klicoveSlovo	N-ligand fluoride organotin(IV) compounds C
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[CBF4AA45B529]
http://linked.open...i/riv/nazevZdroje	Journal of Fluorine Chemistry
http://linked.open...in/vavai/riv/obor	JJ
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Perspective inorganic materials The study of preparation, properties, structure and reactivity of organometallic C,Y- and Y,C,Y- complexes Organometallic Compounds of Divalent Metals of 14th Group
http://linked.open...UplatneniVysledku	2005
http://linked.open...v/svazekPeriodika	126
http://linked.open...iv/tvurceVysledku	Císařová, I. Růžička, A. Novák, P. Brus, Jiří Holeček, J.
http://linked.open...n/vavai/riv/zamer	Progresivní makromolekulární materiály a supramolekulární systémy: syntéza a studium vlastností, jevů a možností využití pro speciální aplikace a moderní technologie Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures
issn	0022-1139
number of pages	8 (xsd:int)

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