About: Anionic polymerization of acrylates. Synthesis of (meth)acrylate di- and triblock copolymers using the Li ester-enolate/tert-alkoxide initiating system

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About: Anionic polymerization of acrylates. Synthesis of (meth)acrylate di- and triblock copolymers using the Li ester-enolate/tert-alkoxide initiating system Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Methacrylate di- and triblock copolymers composed of methyl (MMA), butyl (BuMA), 2-(dimethylamino)ethyl (DMAMA), and 2-ethylhexyl (EtHMA) methacrylates and tert-butyl acrylate (t-BuA) blocks were prepared by ligated anionic polymerization and characterized by SEC and NMR. A possible mechanism of self-termination and reactions of polymethacrylate chains bearing a few terminal acrylate units are briefly discussed. Methacrylate di- and triblock copolymers composed of methyl (MMA), butyl (BuMA), 2-(dimethylamino)ethyl (DMAMA), and 2-ethylhexyl (EtHMA) methacrylates and tert-butyl acrylate (t-BuA) blocks were prepared by ligated anionic polymerization and characterized by SEC and NMR. A possible mechanism of self-termination and reactions of polymethacrylate chains bearing a few terminal acrylate units are briefly discussed. (en) Methakrylátové di- a triblokové kopolymery složené z bloků methyl (MMA), butyl (BuMA), 2-(dimethylamino)ethyl (DMAMA), and 2-ethylhexyl (EtHMA) methakrylátů and tert-butyl akrylátu (t-BuA) byly připraveny %22ligated%22 aniontovou polymerizací a charakterizovány pomocí SEC a NMR. Krátce je diskutován možný mechanismus self-terminace a reakcí polymethakrylátového řetězce s několika terminálními akrylátovými jednotkami. (cs)
Title	Anionic polymerization of acrylates. Synthesis of (meth)acrylate di- and triblock copolymers using the Li ester-enolate/tert-alkoxide initiating system Aniontová polymerizace akrylátů. Syntéza (meth)akrylátových di- a triblokových kopolymerů iniciovaná systémem Li ester-enolát/tert-alkoxid (cs) Anionic polymerization of acrylates. Synthesis of (meth)acrylate di- and triblock copolymers using the Li ester-enolate/tert-alkoxide initiating system (en)
skos:prefLabel	Anionic polymerization of acrylates. Synthesis of (meth)acrylate di- and triblock copolymers using the Li ester-enolate/tert-alkoxide initiating system Aniontová polymerizace akrylátů. Syntéza (meth)akrylátových di- a triblokových kopolymerů iniciovaná systémem Li ester-enolát/tert-alkoxid (cs) Anionic polymerization of acrylates. Synthesis of (meth)acrylate di- and triblock copolymers using the Li ester-enolate/tert-alkoxide initiating system (en)
skos:notation	RIV/61389013:_____/04:00105808!RIV/2005/GA0/A55005/N
http://linked.open.../vavai/riv/strany	344;351
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/01/0513), P(KSK4050111), Z(AV0Z4050913)
http://linked.open...iv/cisloPeriodika	2
http://linked.open...vai/riv/dodaniDat	2005
http://linked.open...aciTvurceVysledku	Kurková, Dana Vlček, Petr Látalová, Petra Otoupalová, Jaroslava Masař, Bohumil Janata, Miroslav Toman, Luděk
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav makromolekulární chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	554692
http://linked.open...ai/riv/idVysledku	RIV/61389013:_____/04:00105808
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	ligated anionic polymerization;block copolymers (en)
http://linked.open.../riv/klicoveSlovo	block copolymers ligated anionic polymerization
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[3E9ACDB255EB]
http://linked.open...i/riv/nazevZdroje	Macromolecules
http://linked.open...in/vavai/riv/obor	CD
http://linked.open...ichTvurcuVysledku	7 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Goal-oriented preparation of chemical compounds with well-defined properties Use of combinations of ionic and radical methods to a synthesis of block copolymers and study of their behavior in thin films
http://linked.open...UplatneniVysledku	2004
http://linked.open...v/svazekPeriodika	37
http://linked.open...iv/tvurceVysledku	Janata, Miroslav Látalová, Petra Vlček, Petr Toman, Luděk Kurková, Dana Masař, Bohumil Otoupalová, Jaroslava
http://linked.open...n/vavai/riv/zamer	Cílená syntéza a studium chemických, fyzikálně-chemických a fyzikálních vlastností makromolekulárních a nadmolekulárních látek a soustav pro vyspělé technologie
issn	0024-9297
number of pages	8 (xsd:int)

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