About: Formation of poly(ethylene glycol) inclusion complexes in aqueous solutions of mixed cyclodextrins.     Goto   Sponge   NotDistinct   Permalink

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Description
  • The addition of modified cyclodextrins (modified CDs) accelerates the precipitation in aqueous solutions of poly(ethylene glycol) (PEG) and .alpha.-cyclodextrin (.alpha.-CD), but the final amount of formed solid complex remains unchanged, with no modified CDs detected by MALDI-TOF mass spectrometry. The unsuitability of kinetic turbidity measurements for determination of binding parameters was confirmed. Theoretical calculations based on a model of a chain of freely accessible binding sites demonstrated that the results do not necessarily contradict the finding that individual modified CD molecules can thread onto PEG chains with the efficiency comparable to that of unmodified .alpha.-CD.
  • The addition of modified cyclodextrins (modified CDs) accelerates the precipitation in aqueous solutions of poly(ethylene glycol) (PEG) and .alpha.-cyclodextrin (.alpha.-CD), but the final amount of formed solid complex remains unchanged, with no modified CDs detected by MALDI-TOF mass spectrometry. The unsuitability of kinetic turbidity measurements for determination of binding parameters was confirmed. Theoretical calculations based on a model of a chain of freely accessible binding sites demonstrated that the results do not necessarily contradict the finding that individual modified CD molecules can thread onto PEG chains with the efficiency comparable to that of unmodified .alpha.-CD. (en)
Title
  • Formation of poly(ethylene glycol) inclusion complexes in aqueous solutions of mixed cyclodextrins.
  • Formation of poly(ethylene glycol) inclusion complexes in aqueous solutions of mixed cyclodextrins. (en)
skos:prefLabel
  • Formation of poly(ethylene glycol) inclusion complexes in aqueous solutions of mixed cyclodextrins.
  • Formation of poly(ethylene glycol) inclusion complexes in aqueous solutions of mixed cyclodextrins. (en)
skos:notation
  • RIV/61389013:_____/03:55033296!RIV/2004/AV0/A55004/N
http://linked.open.../vavai/riv/strany
  • 259;264
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(IAA1050101), Z(AV0Z4050913)
http://linked.open...iv/cisloPeriodika
  • N/A
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 607588
http://linked.open...ai/riv/idVysledku
  • RIV/61389013:_____/03:55033296
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • cyclodextrins; inclusion complexes; phase separation (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [155D4995975C]
http://linked.open...i/riv/nazevZdroje
  • Macromolecular Symposia
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 203
http://linked.open...iv/tvurceVysledku
  • Horský, Jiří
  • Walterová, Zuzana
http://linked.open...n/vavai/riv/zamer
issn
  • 1022-1360
number of pages
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