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  • The dynamic-structural changes and polymer - solvent interactions during the thermotropic phase transition in poly(vinyl methyl ether) (PVME)/D2O solutions in a broad range of polymer concentrations (c = 0.1-60 wt.-%) were studied combining the measurements of 1H NMR spectra, spin-spin (T2) and spin-lattice (T1) relaxation times. Measurements of spin-spin relaxation times T2 of PVME methylene protons have shown that globular structures are more compact in dilute solutions in comparison with semidilute solutions where globules probably contain a certain amount of water.
  • The dynamic-structural changes and polymer - solvent interactions during the thermotropic phase transition in poly(vinyl methyl ether) (PVME)/D2O solutions in a broad range of polymer concentrations (c = 0.1-60 wt.-%) were studied combining the measurements of 1H NMR spectra, spin-spin (T2) and spin-lattice (T1) relaxation times. Measurements of spin-spin relaxation times T2 of PVME methylene protons have shown that globular structures are more compact in dilute solutions in comparison with semidilute solutions where globules probably contain a certain amount of water. (en)
Title
  • 1H NMR relaxation study of polymerůsolvent interactions during thermotropic phase transition in aqueous solutions.
  • 1H NMR relaxation study of polymerůsolvent interactions during thermotropic phase transition in aqueous solutions. (en)
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  • 1H NMR relaxation study of polymerůsolvent interactions during thermotropic phase transition in aqueous solutions.
  • 1H NMR relaxation study of polymerůsolvent interactions during thermotropic phase transition in aqueous solutions. (en)
skos:notation
  • RIV/61389013:_____/03:55033294!RIV/2004/AV0/A55004/N
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  • 229;237
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  • P(KSK4050111)
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  • N/A
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  • 636711
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  • RIV/61389013:_____/03:55033294
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  • NMR; polymer-solvent interactions; poly(vinyl methyl ether)/D2O solution (en)
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  • DE - Spolková republika Německo
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  • [5E291E5BB462]
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  • Macromolecular Symposia
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  • 203
http://linked.open...iv/tvurceVysledku
  • Hanyková, L.
  • Spěváček, Jiří
issn
  • 1022-1360
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