About: Anionic polymerization of acrylates. XII. Polymerization of methyl methacrylate and tert-butyl acrylate initiated with alkyllithiums or methyl 2-lithioisobutyrate in the presence of lithium tert-butoxide.

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About: Anionic polymerization of acrylates. XII. Polymerization of methyl methacrylate and tert-butyl acrylate initiated with alkyllithiums or methyl 2-lithioisobutyrate in the presence of lithium tert-butoxide. Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Ligated anionic polymerization of methyl methacrylate and tert-butyl acrylate initiated either with 1,1-diphenyl-3-methylpentyllithium or .alpha.-methyl styryllithium or methyl 2-isobutyrate stabilized with lithium tert-butoxide was studied at -60.grade.. In combination with DPMPLi, or .alpha.-MStLi, stabilizing efficiency of the alkoxide is negligible. In the presence of ten-fold excess of t-BuOli, MID-Li initiates slow polymerization of MMA with high stability of active centers. Three MMA doses were successively polymerized producing polymers with narrow MWDs in all steps, so that the active centers remained living for more than 4 h. Ligated anionic polymerization of methyl methacrylate and tert-butyl acrylate initiated either with 1,1-diphenyl-3-methylpentyllithium or .alpha.-methyl styryllithium or methyl 2-isobutyrate stabilized with lithium tert-butoxide was studied at -60.grade.. In combination with DPMPLi, or .alpha.-MStLi, stabilizing efficiency of the alkoxide is negligible. In the presence of ten-fold excess of t-BuOli, MID-Li initiates slow polymerization of MMA with high stability of active centers. Three MMA doses were successively polymerized producing polymers with narrow MWDs in all steps, so that the active centers remained living for more than 4 h. (en)
Title	Anionic polymerization of acrylates. XII. Polymerization of methyl methacrylate and tert-butyl acrylate initiated with alkyllithiums or methyl 2-lithioisobutyrate in the presence of lithium tert-butoxide. Anionic polymerization of acrylates. XII. Polymerization of methyl methacrylate and tert-butyl acrylate initiated with alkyllithiums or methyl 2-lithioisobutyrate in the presence of lithium tert-butoxide. (en)
skos:prefLabel	Anionic polymerization of acrylates. XII. Polymerization of methyl methacrylate and tert-butyl acrylate initiated with alkyllithiums or methyl 2-lithioisobutyrate in the presence of lithium tert-butoxide. Anionic polymerization of acrylates. XII. Polymerization of methyl methacrylate and tert-butyl acrylate initiated with alkyllithiums or methyl 2-lithioisobutyrate in the presence of lithium tert-butoxide. (en)
skos:notation	RIV/61389013:_____/02:55023199!RIV/2003/GA0/A55003/N
http://linked.open.../vavai/riv/strany	7179;7184
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/01/0513), P(OC P1.10), Z(AV0Z4050913)
http://linked.open...iv/cisloPeriodika	25
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Vlček, Petr Látalová, Petra Otoupalová, Jaroslava Masař, Bohumil Janata, Miroslav Toman, Luděk
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav makromolekulární chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	638467
http://linked.open...ai/riv/idVysledku	RIV/61389013:_____/02:55023199
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	ligated anionic polymerization; (meth)acrylates; lithium tert-butoxide (en)
http://linked.open.../riv/klicoveSlovo	(meth)acrylates ligated anionic polymerization lithium tert-butoxide
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[116D79E28DEC]
http://linked.open...i/riv/nazevZdroje	Polymer
http://linked.open...in/vavai/riv/obor	CD
http://linked.open...ichTvurcuVysledku	6 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Use of combinations of ionic and radical methods to a synthesis of block copolymers and study of their behavior in thin films http://linked.opendata.cz/resource/domain/vavai/projekt/OC%20P1.10
http://linked.open...UplatneniVysledku	2002
http://linked.open...v/svazekPeriodika	43
http://linked.open...iv/tvurceVysledku	Janata, Miroslav Látalová, Petra Vlček, Petr Toman, Luděk Masař, Bohumil Otoupalová, Jaroslava
http://linked.open...n/vavai/riv/zamer	Cílená syntéza a studium chemických, fyzikálně-chemických a fyzikálních vlastností makromolekulárních a nadmolekulárních látek a soustav pro vyspělé technologie
issn	0032-3861
number of pages	6 (xsd:int)

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