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  • Glasses from Ge.sub.x./sub.As.sub.40-x./sub.Se.sub.60./sub., Ge.sub.x./sub.Sb.sub.40-x./sub.S.sub.60./sub. and Ge.sub.x./sub.Sb.sub40-x./sub.Se.sub.60./sub. families have been investigated by neutron diffraction. The well expressed 'first sharp diffraction peak' of the neutron spectra at Q= 10- 14 nm.sub.-1./sub. has been explained by a pseudo-binary model of the structure of studied chalcogenide glasses. The amplitude of this interference maximum increases with Ge-content in all investigated samples. Experimental radial distribution functions show that the basic structural units, GeS(Se).sub.4./sub. tetrahedra and As(Sb)S.sub.3./sub. or As(Sb)Se.sub.3./sub. pyramids persist in glassy state for the whole range of studied compositions. Crystal-like model distribution functions have been used to describe the short-range order observed. A shortening of heteropolar bonds in S-containing glasses as well as an increase of heteropolar bonds length in Se-containing glasses has been found.
  • Glasses from Ge.sub.x./sub.As.sub.40-x./sub.Se.sub.60./sub., Ge.sub.x./sub.Sb.sub.40-x./sub.S.sub.60./sub. and Ge.sub.x./sub.Sb.sub40-x./sub.Se.sub.60./sub. families have been investigated by neutron diffraction. The well expressed 'first sharp diffraction peak' of the neutron spectra at Q= 10- 14 nm.sub.-1./sub. has been explained by a pseudo-binary model of the structure of studied chalcogenide glasses. The amplitude of this interference maximum increases with Ge-content in all investigated samples. Experimental radial distribution functions show that the basic structural units, GeS(Se).sub.4./sub. tetrahedra and As(Sb)S.sub.3./sub. or As(Sb)Se.sub.3./sub. pyramids persist in glassy state for the whole range of studied compositions. Crystal-like model distribution functions have been used to describe the short-range order observed. A shortening of heteropolar bonds in S-containing glasses as well as an increase of heteropolar bonds length in Se-containing glasses has been found. (en)
Title
  • Neutron diffraction study on the medium and short-range order of ternary chalcogenide glasses.
  • Neutron diffraction study on the medium and short-range order of ternary chalcogenide glasses. (en)
skos:prefLabel
  • Neutron diffraction study on the medium and short-range order of ternary chalcogenide glasses.
  • Neutron diffraction study on the medium and short-range order of ternary chalcogenide glasses. (en)
skos:notation
  • RIV/61389005:_____/99:49020110!RIV/2003/GA0/A49003/N
http://linked.open.../vavai/riv/strany
  • 3669;3676
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GV202/97/K038), Z(AV0Z1048901)
http://linked.open...iv/cisloPeriodika
  • N/A
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 747342
http://linked.open...ai/riv/idVysledku
  • RIV/61389005:_____/99:49020110
http://linked.open...riv/jazykVysledku
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  • neutron diffraction; short-range order; chalcogenide glasses (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [8BC3B3D2DD39]
http://linked.open...i/riv/nazevZdroje
  • Journal of Materials Science
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 34
http://linked.open...iv/tvurceVysledku
  • Lukáš, Petr
  • Mikula, Pavel
  • Arsova, D.
  • Gerasimova, I.
  • Neov, S.
  • Sonntag, R.
  • Pamukchieva, V.
  • Skordeva, E.
http://linked.open...n/vavai/riv/zamer
issn
  • 0022-2461
number of pages
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