About: Large area deposition of boron doped nano-crystalline diamond films at low temperatures using microwave plasma enhanced chemical vapour deposition with linear antenna delivery     Goto   Sponge   NotDistinct   Permalink

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  • We report on the preparation and characterisation of boron (B) doped nano-crystalline diamond (BNCD) layers grown over large areas (up to 50cm x 30cm) and at low substrate temperatures (<650°C) using microwave plasma enhanced chemical vapour deposition apparatus with linear antenna delivery apparatus (MW-LA-PECVD). B-NCD layers were grown in H2/CH4/CO2 and H2/CH4 gas mixtures with added trimethylboron (TMB). Layers with thicknesses of 150nm to 1μm have been prepared with B/C ratios up to 15000ppm over a range of CO2/CH4 ratios to study the effect of oxygen (O) on the incorporation rate of B into the solid phase and the effect on the quality of the BNCD with respect to sp3/sp2 ratio. Experimental results show the reduction of boron acceptor concentration with increasing CO2 concentration. Higher sp3/sp2 ratios were measured by Raman spectroscopy with increasing TMB concentration in the gas phase without CO2.
  • We report on the preparation and characterisation of boron (B) doped nano-crystalline diamond (BNCD) layers grown over large areas (up to 50cm x 30cm) and at low substrate temperatures (<650°C) using microwave plasma enhanced chemical vapour deposition apparatus with linear antenna delivery apparatus (MW-LA-PECVD). B-NCD layers were grown in H2/CH4/CO2 and H2/CH4 gas mixtures with added trimethylboron (TMB). Layers with thicknesses of 150nm to 1μm have been prepared with B/C ratios up to 15000ppm over a range of CO2/CH4 ratios to study the effect of oxygen (O) on the incorporation rate of B into the solid phase and the effect on the quality of the BNCD with respect to sp3/sp2 ratio. Experimental results show the reduction of boron acceptor concentration with increasing CO2 concentration. Higher sp3/sp2 ratios were measured by Raman spectroscopy with increasing TMB concentration in the gas phase without CO2. (en)
Title
  • Large area deposition of boron doped nano-crystalline diamond films at low temperatures using microwave plasma enhanced chemical vapour deposition with linear antenna delivery
  • Large area deposition of boron doped nano-crystalline diamond films at low temperatures using microwave plasma enhanced chemical vapour deposition with linear antenna delivery (en)
skos:prefLabel
  • Large area deposition of boron doped nano-crystalline diamond films at low temperatures using microwave plasma enhanced chemical vapour deposition with linear antenna delivery
  • Large area deposition of boron doped nano-crystalline diamond films at low temperatures using microwave plasma enhanced chemical vapour deposition with linear antenna delivery (en)
skos:notation
  • RIV/61389005:_____/14:00431502!RIV15-AV0-61389005
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(LM2011019), P(LM2011026)
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  • AUG
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  • 25651
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  • RIV/61389005:_____/14:00431502
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  • large area; low temperature; boron doped nano-crystalline diamond; linear antenna MW PE CVD (en)
http://linked.open.../riv/klicoveSlovo
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  • CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV
  • [3ADA2DE9CCEC]
http://linked.open...i/riv/nazevZdroje
  • Diamond and Related Materials
http://linked.open...in/vavai/riv/obor
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http://linked.open...vavai/riv/projekt
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  • 47
http://linked.open...iv/tvurceVysledku
  • Janíček, P.
  • Jäger, Aleš
  • Mistrík, J.
  • Vacík, Jiří
  • Hubík, Pavel
  • Fekete, Ladislav
  • Taylor, Andrew
  • Mortet, Vincent
http://linked.open...ain/vavai/riv/wos
  • 000340318100004
issn
  • 0925-9635
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.diamond.2014.05.002
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