About: Structural Consequences of Duplicitous Chemical Relation of Cobalt and Fullerene in Mixture

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The factors driving the structure organization in the Co-C-60 films fabricated by simultaneous deposition were analyzed. It is shown that phase separation is the major factor yielding the nanocomposite (NC) structure in the co-deposited film (fcc-Co nanocrystals immersed into C-60-based matrix). The phase separation is accompanied by accumulation of compressive stress in the film mixture. The metal-fullerene chemical bonding is the next important factor responsible for creation of the -Co-C-60- polymer in the NC matrix. Thermal treatment can significantly influence the structure organization through enhancement of the main factors (phase separation or chemical bonding) that yields the remarkable structural effects. In particular, annealing at the elevated temperatures (T-a = 300-500 degrees C) induces the regular carbon structure transformations in the NC matrix followed by creation of carbon nanotubes or graphitic-like shells (depending on T-a). The C-structure transformation is controlled by catalytic effect of Co atoms retaining in the NC matrix. The factors driving the structure organization in the Co-C-60 films fabricated by simultaneous deposition were analyzed. It is shown that phase separation is the major factor yielding the nanocomposite (NC) structure in the co-deposited film (fcc-Co nanocrystals immersed into C-60-based matrix). The phase separation is accompanied by accumulation of compressive stress in the film mixture. The metal-fullerene chemical bonding is the next important factor responsible for creation of the -Co-C-60- polymer in the NC matrix. Thermal treatment can significantly influence the structure organization through enhancement of the main factors (phase separation or chemical bonding) that yields the remarkable structural effects. In particular, annealing at the elevated temperatures (T-a = 300-500 degrees C) induces the regular carbon structure transformations in the NC matrix followed by creation of carbon nanotubes or graphitic-like shells (depending on T-a). The C-structure transformation is controlled by catalytic effect of Co atoms retaining in the NC matrix. (en)
Title	Structural Consequences of Duplicitous Chemical Relation of Cobalt and Fullerene in Mixture Structural Consequences of Duplicitous Chemical Relation of Cobalt and Fullerene in Mixture (en)
skos:prefLabel	Structural Consequences of Duplicitous Chemical Relation of Cobalt and Fullerene in Mixture Structural Consequences of Duplicitous Chemical Relation of Cobalt and Fullerene in Mixture (en)
skos:notation	RIV/61389005:_____/12:00384958!RIV13-AV0-61389005
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(GA106/09/1264), P(GAP107/11/1856), P(KAN400480701)
http://linked.open...iv/cisloPeriodika	4-7
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Vacík, Jiří Lavrentiev, Vasyl
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav jaderné fyziky AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	171814
http://linked.open...ai/riv/idVysledku	RIV/61389005:_____/12:00384958
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	fullerene; cobalt; chemical bonding; nanostructure; self-organization (en)
http://linked.open.../riv/klicoveSlovo	cobalt self-organization fullerene nanostructure chemical bonding
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[82DDE3D2970C]
http://linked.open...i/riv/nazevZdroje	Fullerenes, Nanotubes, and Carbon Nanostructures
http://linked.open...in/vavai/riv/obor	BG
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Fabrication and structure control of functional metal nano-particles on oxide ceramics NANOSTRUCTURES BASED ON CARBON AND POLYMERS FOR APPLICATION IN BIOELECTRONIC AND MEDICINE Metal-fullerene nanocomposites and their biological applications
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	20
http://linked.open...iv/tvurceVysledku	Lavrentiev, Vasyl Vacík, Jiří Naramoto, H.
http://linked.open...ain/vavai/riv/wos	000304297500006
issn	1536-383X
number of pages	7 (xsd:int)
http://bibframe.org/vocab/doi	10.1080/1536383X.2012.655118

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