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Description
| - New ionic manganese(II/III), manganese(III) and iron(II/III) complexes of the formula [Mn-II(H2O)(2)(phen)(2)]{[Mn-III(dipic)(2)]}(2)center dot 7H(2)O, (dmphenH)[Mn-III(dipic)(2)]center dot 2H(2)O, (2,2'-bipyH)[Mn-III(dipic)(2)]center dot 3H(2)O, (4,4'-bipyH)[Mn-III(dipic)(2)]center dot 4H(2)O, [Fe-II(phen)(3)]{[Fe-III(dipic)(2)]}(2)center dot 4.83H(2)O and [Fe-II(2,2'-bipy)(3)]{[Fe-III(dipic)(2)]}(2)center dot 6.11H(2)O where dipic(2-) = pyridine-2,6-dicarboxylate anion, phen = 1,10-phenanthroline, dmphenH = 2,9-dimethyl-1,10-phenanthrolinium cation, 2,2'-bipyH = 2-(2-pyridyl)pyridinium cation, 4,4'-bipyH = 4-(4-pyridyl)pyridinium cation, have been prepared and characterized by the single-crystal X-ray structure analysis, infrared spectroscopy, and by magnetic susceptibility and magnetization measurements. A zero field splitting was found in the Mn(III) dipicolinates while an antiferromagnetic exchange interaction was present in the Fe(III) dipicolinates.
- New ionic manganese(II/III), manganese(III) and iron(II/III) complexes of the formula [Mn-II(H2O)(2)(phen)(2)]{[Mn-III(dipic)(2)]}(2)center dot 7H(2)O, (dmphenH)[Mn-III(dipic)(2)]center dot 2H(2)O, (2,2'-bipyH)[Mn-III(dipic)(2)]center dot 3H(2)O, (4,4'-bipyH)[Mn-III(dipic)(2)]center dot 4H(2)O, [Fe-II(phen)(3)]{[Fe-III(dipic)(2)]}(2)center dot 4.83H(2)O and [Fe-II(2,2'-bipy)(3)]{[Fe-III(dipic)(2)]}(2)center dot 6.11H(2)O where dipic(2-) = pyridine-2,6-dicarboxylate anion, phen = 1,10-phenanthroline, dmphenH = 2,9-dimethyl-1,10-phenanthrolinium cation, 2,2'-bipyH = 2-(2-pyridyl)pyridinium cation, 4,4'-bipyH = 4-(4-pyridyl)pyridinium cation, have been prepared and characterized by the single-crystal X-ray structure analysis, infrared spectroscopy, and by magnetic susceptibility and magnetization measurements. A zero field splitting was found in the Mn(III) dipicolinates while an antiferromagnetic exchange interaction was present in the Fe(III) dipicolinates. (en)
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Title
| - Synthesis, structure and magnetism of manganese and iron dipicolinates with N,N '-donor ligands
- Synthesis, structure and magnetism of manganese and iron dipicolinates with N,N '-donor ligands (en)
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skos:prefLabel
| - Synthesis, structure and magnetism of manganese and iron dipicolinates with N,N '-donor ligands
- Synthesis, structure and magnetism of manganese and iron dipicolinates with N,N '-donor ligands (en)
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skos:notation
| - RIV/61388980:_____/15:00439785!RIV15-AV0-61388980
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388980:_____/15:00439785
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Manganese; Iron; Dipicolinate complexes; Crystal structure; Magnetism (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Dlháň, L.
- Koman, M.
- Uhrecký, Róbert
- Pavlík, J.
- Svoboda, I.
- Boca, R.
- Moncol, J.
- Růžičková, Z.
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1016/j.ica.2014.10.006
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