About: Additivity of Interligand Substituent Effects for the Isoelectronic [(eta(5)-C6H7)Fe(eta(6)-MenC6H6-n)](+) and [(eta(5)-C5H5)Fe(eta(6)-MenC6H6-n)](+) Sandwich Cations     Goto   Sponge   NotDistinct   Permalink

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  • Complete assignments of chemical shifts in the H-1 and C-13 NMR spectra for a contiguous series of [(eta(5)-C6H7)Fe(eta(6)-MenC6H6-n)](+) and [(eta(5)-C5H5)Fe(eta(6)-MenC6H6-n)](+) cations (where n = 0-6) are reported. The spectra revealed a straightforward linear correlation between delta(H-1) or delta(C-13) parameters of the cyclohexadienyl (Chd) and cyclopentadienyl (Cp) rings and the number of arene methyl substituents (n), which is consistent with an additive character of the interligand substituent effect and its transmission onto the second (Chd or Cp) ring via the Fe-II center.
  • Complete assignments of chemical shifts in the H-1 and C-13 NMR spectra for a contiguous series of [(eta(5)-C6H7)Fe(eta(6)-MenC6H6-n)](+) and [(eta(5)-C5H5)Fe(eta(6)-MenC6H6-n)](+) cations (where n = 0-6) are reported. The spectra revealed a straightforward linear correlation between delta(H-1) or delta(C-13) parameters of the cyclohexadienyl (Chd) and cyclopentadienyl (Cp) rings and the number of arene methyl substituents (n), which is consistent with an additive character of the interligand substituent effect and its transmission onto the second (Chd or Cp) ring via the Fe-II center. (en)
Title
  • Additivity of Interligand Substituent Effects for the Isoelectronic [(eta(5)-C6H7)Fe(eta(6)-MenC6H6-n)](+) and [(eta(5)-C5H5)Fe(eta(6)-MenC6H6-n)](+) Sandwich Cations
  • Additivity of Interligand Substituent Effects for the Isoelectronic [(eta(5)-C6H7)Fe(eta(6)-MenC6H6-n)](+) and [(eta(5)-C5H5)Fe(eta(6)-MenC6H6-n)](+) Sandwich Cations (en)
skos:prefLabel
  • Additivity of Interligand Substituent Effects for the Isoelectronic [(eta(5)-C6H7)Fe(eta(6)-MenC6H6-n)](+) and [(eta(5)-C5H5)Fe(eta(6)-MenC6H6-n)](+) Sandwich Cations
  • Additivity of Interligand Substituent Effects for the Isoelectronic [(eta(5)-C6H7)Fe(eta(6)-MenC6H6-n)](+) and [(eta(5)-C5H5)Fe(eta(6)-MenC6H6-n)](+) Sandwich Cations (en)
skos:notation
  • RIV/61388980:_____/14:00438737!RIV15-GA0-61388980
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GAP207/11/0705)
http://linked.open...iv/cisloPeriodika
  • 11
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 1628
http://linked.open...ai/riv/idVysledku
  • RIV/61388980:_____/14:00438737
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • iron complexes; exchange; ligand (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [85D0B3EEAB31]
http://linked.open...i/riv/nazevZdroje
  • Organometallics
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 33
http://linked.open...iv/tvurceVysledku
  • Turek, Jan
  • Štíbr, Bohumil
  • Olejník, Roman
http://linked.open...ain/vavai/riv/wos
  • 000337121700028
issn
  • 0276-7333
number of pages
http://bibframe.org/vocab/doi
  • 10.1021/om500165w
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