About: Reactions associated with arene replacement in bis-(arene) iron complexes

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Iron is one of the most abundant elements on the Earth and its chemistry has been therefore rapidly developed. As a part of the chemistry these complexes, a short review on the synthesis of bis-(arene) iron complexes and reactions associated with direct and indirect replacement of arene ligands in these complexes is presented. These reactions lead to a broad variety of novel iron sandwich compounds that now play an important role in the development of specific areas of metaloorganic and metallacarborane chemistry of iron. The review comprises recent synthetic routes and approaches to iron sandwich complexes, of which the most significant have been arene and cyclohexadienyl ferradicarba- and ferratricarba-boranes, together with new types of piano-stool structured compounds. The reader will also find references to methods of structural characterization of individual compounds in this area of chemistry. Iron is one of the most abundant elements on the Earth and its chemistry has been therefore rapidly developed. As a part of the chemistry these complexes, a short review on the synthesis of bis-(arene) iron complexes and reactions associated with direct and indirect replacement of arene ligands in these complexes is presented. These reactions lead to a broad variety of novel iron sandwich compounds that now play an important role in the development of specific areas of metaloorganic and metallacarborane chemistry of iron. The review comprises recent synthetic routes and approaches to iron sandwich complexes, of which the most significant have been arene and cyclohexadienyl ferradicarba- and ferratricarba-boranes, together with new types of piano-stool structured compounds. The reader will also find references to methods of structural characterization of individual compounds in this area of chemistry. (en)
Title	Reactions associated with arene replacement in bis-(arene) iron complexes Reactions associated with arene replacement in bis-(arene) iron complexes (en)
skos:prefLabel	Reactions associated with arene replacement in bis-(arene) iron complexes Reactions associated with arene replacement in bis-(arene) iron complexes (en)
skos:notation	RIV/61388980:_____/12:00382794!RIV13-GA0-61388980
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(GAP207/11/0705)
http://linked.open...iv/cisloPeriodika	OCTOBER
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Štíbr, Bohumil
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	164185
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/12:00382794
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	arene replacement reactions; ferracarboranes; iron-iron arene complexes; iron cyclohexadienyl complexes; metallacarboranes (en)
http://linked.open.../riv/klicoveSlovo	arene replacement reactions ferracarboranes iron cyclohexadienyl complexes iron-iron arene complexes metallacarboranes
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[D37920EE9A13]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	1 (xsd:int)
http://linked.open...vavai/riv/projekt	Carborane-modified iron-arene complexes
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	716
http://linked.open...iv/tvurceVysledku	Štíbr, Bohumil
http://linked.open...ain/vavai/riv/wos	000307821700001
issn	0022-328X
number of pages	5 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.jorganchem.2012.05.046

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