About: Anion recognition by calix[4]arene-based p-nitrophenyl amides     Goto   Sponge   NotDistinct   Permalink

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Description
  • Calix[4]arene derivatives immobilised in the cone conformation and bearing p-nitrophenyl moieties appended to the upper rim via the amide functions have been synthesised and applied as anion receptors. The H-1 NMR and UV/Vis complexation studies towards selected anions proved that the complexation ability depends considerably on the substitution pattern of the calixarene core. Thus, the proximal diamide derivative has a complexation constant for H2PO4- by one order of magnitude higher than the distal analogue.
  • Calix[4]arene derivatives immobilised in the cone conformation and bearing p-nitrophenyl moieties appended to the upper rim via the amide functions have been synthesised and applied as anion receptors. The H-1 NMR and UV/Vis complexation studies towards selected anions proved that the complexation ability depends considerably on the substitution pattern of the calixarene core. Thus, the proximal diamide derivative has a complexation constant for H2PO4- by one order of magnitude higher than the distal analogue. (en)
Title
  • Anion recognition by calix[4]arene-based p-nitrophenyl amides
  • Anion recognition by calix[4]arene-based p-nitrophenyl amides (en)
skos:prefLabel
  • Anion recognition by calix[4]arene-based p-nitrophenyl amides
  • Anion recognition by calix[4]arene-based p-nitrophenyl amides (en)
skos:notation
  • RIV/61388980:_____/12:00379782!RIV13-GA0-61388980
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/09/0691), P(IAAX08240901), S, Z(AV0Z40320502)
http://linked.open...iv/cisloPeriodika
  • 6
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
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http://linked.open...dnocenehoVysledku
  • 122801
http://linked.open...ai/riv/idVysledku
  • RIV/61388980:_____/12:00379782
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • calixarenes; anion recognition; receptor; complexation; UV/Vis titration (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [1D9D3916AD65]
http://linked.open...i/riv/nazevZdroje
  • Tetrahedron Letters
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http://linked.open...v/svazekPeriodika
  • 53
http://linked.open...iv/tvurceVysledku
  • Lang, Kamil
  • Lhoták, P.
  • Flídrová, K.
  • Tkadlecová, M.
http://linked.open...ain/vavai/riv/wos
  • 000300527600018
http://linked.open...n/vavai/riv/zamer
issn
  • 0040-4039
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.tetlet.2011.11.127
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