About: Temperature-induced phase transformations of the small-pore zirconosilicate Na2ZrSi2O7 center dot H2O     Goto   Sponge   NotDistinct   Permalink

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  • DTA-TG and powder XRD analyses are used to study the thermal behavior and the occurring upon heating structural transformations of the small-pore zirconosilicate Na2ZrSi2O7 center dot H2O. Upon heating the monoclinic structure of the title compound converts into orthorhombic one, however preserving the initial topology. The heating above 800 degrees C leads to gradual distortion of the Si2O7 pyrogroups configuration and causes transformation of the [M2T6] into [M2T4] composite building units (CBUs) and irreversible transition of the orthorhombic compound into a phase with denser triclinic structure. (C) 2010 Elsevier Masson SAS. All rights reserved.
  • DTA-TG and powder XRD analyses are used to study the thermal behavior and the occurring upon heating structural transformations of the small-pore zirconosilicate Na2ZrSi2O7 center dot H2O. Upon heating the monoclinic structure of the title compound converts into orthorhombic one, however preserving the initial topology. The heating above 800 degrees C leads to gradual distortion of the Si2O7 pyrogroups configuration and causes transformation of the [M2T6] into [M2T4] composite building units (CBUs) and irreversible transition of the orthorhombic compound into a phase with denser triclinic structure. (C) 2010 Elsevier Masson SAS. All rights reserved. (en)
Title
  • Temperature-induced phase transformations of the small-pore zirconosilicate Na2ZrSi2O7 center dot H2O
  • Temperature-induced phase transformations of the small-pore zirconosilicate Na2ZrSi2O7 center dot H2O (en)
skos:prefLabel
  • Temperature-induced phase transformations of the small-pore zirconosilicate Na2ZrSi2O7 center dot H2O
  • Temperature-induced phase transformations of the small-pore zirconosilicate Na2ZrSi2O7 center dot H2O (en)
skos:notation
  • RIV/61388980:_____/11:00436196!RIV15-AV0-61388980
http://linked.open...avai/riv/aktivita
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  • Z(AV0Z40320502)
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  • 5
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  • 234613
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  • RIV/61388980:_____/11:00436196
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  • Sodium zirconosilicate; Small-pore material; Topotactic dehydration; Phase transition (en)
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  • FR - Francouzská republika
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  • [B41618F4C1F0]
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  • Solid State Sciences
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  • 13
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  • Bezdička, Petr
  • Bakardjieva, Snejana
  • Noriaki, N.
  • Petrova, N. R.
  • Vladislav, K. K.
http://linked.open...ain/vavai/riv/wos
  • 000291081900062
http://linked.open...n/vavai/riv/zamer
issn
  • 1293-2558
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.solidstatesciences.2010.06.018
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