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  • An industrial liquid liquid extraction process for reprocessing of spent nuclear fuel will inevitably lead to radiolysis of the phases, since the process streams contain highly radioactive species. Solvents containing one of the BTBP (6,6'-bis(5,6-dialkyl-[1,2,4]-triazin-3-yl)-2,2'-bipyridine) molecules intended for the separation of trivalent actinides (An) from lanthanides (Ln), the so called C5-BTBP, have shown a dramatic decrease in both distribution ratios and An/Ln separation factor when irradiated; hence, the molecule is highly unstable towards radiolysis.
  • An industrial liquid liquid extraction process for reprocessing of spent nuclear fuel will inevitably lead to radiolysis of the phases, since the process streams contain highly radioactive species. Solvents containing one of the BTBP (6,6'-bis(5,6-dialkyl-[1,2,4]-triazin-3-yl)-2,2'-bipyridine) molecules intended for the separation of trivalent actinides (An) from lanthanides (Ln), the so called C5-BTBP, have shown a dramatic decrease in both distribution ratios and An/Ln separation factor when irradiated; hence, the molecule is highly unstable towards radiolysis. (en)
Title
  • Semi-quantitative and quantitative studies on the gamma radiolysis of C5-BTBP
  • Semi-quantitative and quantitative studies on the gamma radiolysis of C5-BTBP (en)
skos:prefLabel
  • Semi-quantitative and quantitative studies on the gamma radiolysis of C5-BTBP
  • Semi-quantitative and quantitative studies on the gamma radiolysis of C5-BTBP (en)
skos:notation
  • RIV/61388980:_____/11:00372096!RIV12-AV0-61388980
http://linked.open...avai/riv/aktivita
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  • Z(AV0Z40320502)
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  • 2
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  • 228814
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  • RIV/61388980:_____/11:00372096
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  • radiolysis; degradation product; solvent extraction; partitioning (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [C73D4AA3E523]
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  • Radiochimica acta
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  • 99
http://linked.open...iv/tvurceVysledku
  • Ekberg, C.
  • Fermvik, A.
  • Grüner, Bohumír
  • Kvíčalová, Magdalena
http://linked.open...ain/vavai/riv/wos
  • 000287983400006
http://linked.open...n/vavai/riv/zamer
issn
  • 0033-8230
number of pages
http://bibframe.org/vocab/doi
  • 10.1524/ract.2011.1800
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