About: Mesoporous titanium-manganese dioxide for sulphur mustard and soman decontamination

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Titanium(IV)-manganese(IV) nano-dispersed oxides were prepared by a homogeneous hydrolysis of potassium permanganate and titanium(IV) oxo-sulphate with 2-chloroacetamide. Synthesised samples were characterised using Brunauer-Emmett-Teller (BET) surface area and Barrett-Joiner-Halenda porosity (BJH), X-ray diffraction (XRD), infrared spectroscopy (IR), and scanning electron microscopy (SEM). These oxides were taken for an experimental evaluation of their reactivity with sulphur mustard (HD or bis(2-chloroethyl)sulphide) and soman (GD or (3,3'-dimethylbutan-2-yl)-methylphosphono-fluoridate). Mn(4+) content affects the decontamination activity; with increasing Mn(4+) content the activity increases for sulphur mustard and decreases for soman. The best decontamination activities for sulphur mustard and soman were observed for samples TiMn_37 with 18.6 wt.% Mn and TiMn_5 with 2.1 wt.% Mn, respectively. Titanium(IV)-manganese(IV) nano-dispersed oxides were prepared by a homogeneous hydrolysis of potassium permanganate and titanium(IV) oxo-sulphate with 2-chloroacetamide. Synthesised samples were characterised using Brunauer-Emmett-Teller (BET) surface area and Barrett-Joiner-Halenda porosity (BJH), X-ray diffraction (XRD), infrared spectroscopy (IR), and scanning electron microscopy (SEM). These oxides were taken for an experimental evaluation of their reactivity with sulphur mustard (HD or bis(2-chloroethyl)sulphide) and soman (GD or (3,3'-dimethylbutan-2-yl)-methylphosphono-fluoridate). Mn(4+) content affects the decontamination activity; with increasing Mn(4+) content the activity increases for sulphur mustard and decreases for soman. The best decontamination activities for sulphur mustard and soman were observed for samples TiMn_37 with 18.6 wt.% Mn and TiMn_5 with 2.1 wt.% Mn, respectively. (en)
Title	Mesoporous titanium-manganese dioxide for sulphur mustard and soman decontamination Mesoporous titanium-manganese dioxide for sulphur mustard and soman decontamination (en)
skos:prefLabel	Mesoporous titanium-manganese dioxide for sulphur mustard and soman decontamination Mesoporous titanium-manganese dioxide for sulphur mustard and soman decontamination (en)
skos:notation	RIV/61388980:_____/11:00370934!RIV12-AV0-61388980
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/08/0334), Z(AV0Z40320502)
http://linked.open...iv/cisloPeriodika	11
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Bludská, Jana Štengl, Václav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	211650
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/11:00370934
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	oxides; chemical synthesis; X-Ray diffraction; raman spectroscopy; infrared spectroscopy (en)
http://linked.open.../riv/klicoveSlovo	oxides infrared spectroscopy raman spectroscopy X-Ray diffraction chemical synthesis
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[3B5D88059DCB]
http://linked.open...i/riv/nazevZdroje	Materials Research Bulletin
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Photocatalytic materials for destruction warfare agents
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	46
http://linked.open...iv/tvurceVysledku	Bludská, Jana Štengl, Václav Němec, T. Opluštil, F.
http://linked.open...ain/vavai/riv/wos	000296038700053
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí
issn	0025-5408
number of pages	7 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.materresbull.2011.07.003

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